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Small honeycomb activated carbon Zhejiang Because the aluminum oxide tetrahedron of zeolite has a negative charge, and the skeleton hole contains cations, a strong electric field is formed around the cations. Therefore, the adsorption force of zeolite not only has a strong dispersion force, but also has a large electrostatic force. It is precisely because of this electrostatic relationship that zeolites have preferential selective adsorption on polar, unsaturated and polarizable molecules. It can strongly adsorb molecules containing polar groups such as hydroxyl ion, ammonium ion and other polarizable groups, especially water, which can form hydrogen bonds with aluminum silicon skeleton, so zeolite has strong water absorption. It can still adsorb even under low relative humidity and concentration, and its water absorption is higher than that of silica gel and activated alumina. The main material of honeycomb zeolite adsorbent is natural zeolite. The manufacturer of zeolite is composed of silica Inorganic microporous material composed of al_2o_3 and alkaline metal or alkaline earth metal, with inner pore volume accounting for 40-50% of the total volume and specific surface area of 100-500 m2/g, is characterized by high temperature resistance, non flammability, good thermal stability and hydrothermal stability. It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and can be regenerated at high temperature. Compared with honeycomb activated carbon, its performance is about 25% of its efficiency, However, it is widely used in the fields of adsorption, separation, catalysis and environment due to its high temperature resistance and difficult ignition. It is more suitable for the treatment of organic waste gas with large air volume and low concentration.
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The zeolite wheel adsorption purification device is a gas purification device that can continuously perform adsorption and desorption operations. Small honeycomb activated carbon high quality The two sides of the zeolite runner are divided into three areas by special sealing devices: adsorption area, desorption (regeneration) area and cooling area. The working process of the system is as follows: the zeolite runner rotates continuously at a low speed and circulates through the adsorption area, desorption (regeneration) area and cooling area; When the exhaust gas with low concentration and large air volume continuously passes through the adsorption area of the runner, VOCs in the exhaust gas are adsorbed by the zeolite of the runner, and the gas purified by adsorption is directly discharged; The organic solvent adsorbed by the wheel is sent to the desorption (regeneration) area along with the rotation of the wheel, and then continuously passes through the desorption area with small amount of hot air, high quality Zhejiang VOCs adsorbed on the runner are thermally desorbed in the desorption area to achieve regeneration, and VOCs waste gas is discharged with hot air; After the runner is transferred to the cooling area for cooling, it can be re adsorbed. With the continuous rotation of the runner, adsorption, desorption and cooling cycles are carried out to ensure the continuous and stable operation of waste gas treatment
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The main material of honeycomb zeolite molecular sieve is natural zeolite, which is an inorganic microporous material composed of SiO2, Al2O3 and alkaline metal or alkaline earth metal. Its inner pore volume accounts for 40-50% of the total volume, and its specific surface area is 300-1000 m2/g, which has the characteristics of high temperature resistance, non flammability, good thermal stability and hydrothermal stability, Small honeycomb activated carbon Zhejiang It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and can be regenerated at high temperature. Its efficiency is 40% higher than that of similar activated carbon. It is widely used in the fields of adsorption, separation, catalysis and environment, and is more suitable for the treatment of organic waste gas with large air volume and low concentration. Small honeycomb activated carbon high quality The adsorption material has a stable ozone decomposition ability, which significantly improves the decomposition efficiency of VOCs. The adsorption material first forms a special structural effect through the combination design of silver and manganese, which can decompose ozone into active oxygen atoms, and then react with VOCs molecules to form carbon dioxide and water.
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The holes and channels inside the zeolite crystal are uniform and fixed in size, and the diameter of the holes is generally 6~15A. Small honeycomb activated carbon Zhejiang Only molecules with smaller diameter can enter the cavity through the zeolite channel and be adsorbed, while large molecules cannot enter the cavity and be adsorbed. Zeolite is also called molecular sieve because of its selective adsorption performance. However, silica gel, activated carbon and other adsorbents have no selective adsorption and screening performance due to their non uniformly fixed pore sizes and large changes. Shunyi zeolite filter material price. Because the silicon (aluminum) oxygen tetrahedron of natural zeolite crystal has many holes and channels, which occupy cations and water molecules. When some other goods are completely dehydrated after baking, the crystal skeleton is not damaged, but forms large holes on the inner surface, which can absorb and store a large number of molecules, so it has the characteristics of large adsorption capacity and high selectivity. Small honeycomb activated carbon high quality In different zeolite minerals, the proportion of silicon and aluminum is different, and the different proportion will cause some characteristics of zeolite changes, such as ion exchange and acid resistance.
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Because there are uniform small internal pores in the molecular sieve structure, Small honeycomb activated carbon Zhejiang When the molecular linear degree of reactants and products is close to the pore size of the crystal, the selectivity of catalytic reaction often depends on the corresponding size of the molecule and pore size. This selectivity is called shape selective catalysis. There are two mechanisms leading to shape selectivity. One is caused by the difference of diffusion coefficient of molecules participating in the reaction in the pore cavity, which is called mass transfer selectivity; The other is caused by the space limitation of the transition state of the catalytic reaction, which is called transition state selectivity. Molecular sieve has clear pore cavity distribution, extremely high internal surface area (600m2/s), good thermal stability (1000 ℃), and adjustable acid site center. The acidity of molecular sieve mainly comes from three coordinated aluminum atoms and aluminum ions (AlO)+on the framework and in the pores. The OH based acid sensitive site center on the molecular sieve HY obtained by ion exchange, and the aluminum ion outside the framework will strengthen the acid site, forming the L acid site center. Polyvalent cations such as Ca2+, Mg2+and La3+can show the acid site center after exchange. The reduction of transition metal ions such as Cu2+and Ag+can also form acid site centers. In general, the higher the Al/Si ratio, the higher the specific activity of OH group. The modification of zeolite acidity can introduce protons through direct exchange of dilute hydrochloric acid. Small honeycomb activated carbon high quality This method often leads to dealumination of molecular sieve framework. So NaY will become NH4Y and then HY.
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Honeycomb zeolite molecular sieve has the crystal structure and characteristics, the surface is a solid skeleton, and the internal holes can play the role of adsorption molecules. There are channels between the holes to connect with each other, and molecules pass through the channels. Due to the crystalline nature of the pores, the pore size distribution of the molecular sieve is very uniform. Molecular sieves selectively adsorb molecules according to the size of holes in their crystals, that is, they adsorb molecules of a certain size and repel molecules of larger substances, so they are vividly called "molecular sieves". The adsorption or repulsion function of molecular sieves is affected by the molecular electricity. Synthetic zeolite has the special function of selective adsorption according to molecular size and polarity, Small honeycomb activated carbon production Therefore, gas or liquid can be dried or purified, which is also the basis for molecular sieve separation. Synthetic zeolite can meet the extensive demand of industry for adsorption and selective products, Zhejiang Small honeycomb activated carbon It is also widely used in industrial separation to synthesize zeolite molecular sieves. Advantages of UOP molecular sieve