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The main components of zeolite are: silicon and aluminum, which have adsorption capacity and can be used as adsorbent; Zeolite runner is to use the specific pore size of zeolite to have the ability of adsorption and desorption for organic pollutants, so that VOCs waste gas with low concentration and large air volume can be concentrated and converted into low air volume and high concentration gas by the zeolite runner, which can reduce the operating cost of the back-end final treatment equipment. Honeycomb activated carbon Beijing The characteristics of the device are suitable for treating waste gas with large flow, low concentration and various organic components. The disadvantage is high initial investment. The zeolite wheel adsorption purification device is a gas purification device that can continuously perform adsorption and desorption operations. The two sides of the zeolite runner are divided into three areas by special sealing devices: adsorption area, desorption (regeneration) area and cooling area. Honeycomb activated carbon high quality The working process of the system is as follows: the zeolite runner rotates continuously at a low speed and circulates through the adsorption area, desorption (regeneration) area and cooling area; When the exhaust gas with low concentration and large air volume continuously passes through the adsorption area of the runner, VOCs in the exhaust gas are adsorbed by the zeolite of the runner, and the gas purified by adsorption is directly discharged; The organic solvent adsorbed by the wheel is sent to the desorption (regeneration) area with the rotation of the runner, and then the small amount of hot air continuously passes through the desorption area. The VOCs adsorbed on the runner are thermally desorbed in the desorption area to achieve regeneration, and the VOCs waste gas is discharged together with the hot air; After the runner is transferred to the cooling area for cooling, the adsorption can be carried out again. With the continuous rotation of the runner, the adsorption, desorption and cooling cycles are carried out to ensure the continuous and stable operation of waste gas treatment.
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Honeycomb activated carbon high quality There are cavities and channels in the crystal structure of zeolite with large adsorption capacity, whose volume accounts for more than 50% of the total volume of zeolite crystals. Moreover, the micropores of zeolite are evenly distributed, and the pore size is small, which is equivalent to the molecular size of general substances. The internal surface area of zeolite crystals can reach more than 1000 square meters. Therefore, the adsorption capacity of zeolite is particularly large. The main material of honeycomb zeolite adsorbent is natural zeolite. The manufacturer of zeolite is composed of silica Inorganic microporous material composed of al_2o_3 and alkaline metal or alkaline earth metal, with inner pore volume accounting for 40-50% of the total volume and specific surface area of 100-500 m2/g, is characterized by high temperature resistance, non flammability, good thermal stability and hydrothermal stability. It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and can be regenerated at high temperature. Compared with honeycomb activated carbon, its performance is about 25% of its efficiency, However, it is widely used in the fields of adsorption, separation, catalysis and environment due to its high temperature resistance and difficult ignition. It is more suitable for the treatment of organic waste gas with large air volume and low concentration.
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Honeycomb activated carbon high quality With the deepening of research, zeolite molecular sieves have gradually moved from laboratory to industrial application. Due to its powerful performance, it can be integrated with the reactor. In membrane catalytic reaction, reaction and separation are coupled. At present, the application fields of zeolite membrane are pervaporation, gas separation and membrane reactor. It is the needs of human practical activities and the development of application fields that constantly promote the development of zeolite molecular sieves. From natural zeolite to synthetic zeolite, from low silica zeolite to high silica zeolite; From silicoaluminium molecular sieve to aluminophosphate molecular sieve; From super micropore to mesoporous material; From inorganic porous frameworks to MOFs, and recently emerging macroporous materials, the yield has been effectively improved, and the synthesis cost and environmental pollution have been reduced
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Honeycomb activated carbon high quality Technical performance and characteristics: simple structure, convenient maintenance and long service life; High absorption and desorption efficiency, so that VOCss waste gas with high air volume and low concentration can be converted into low air volume and high concentration waste gas, reducing the cost of back-end final treatment equipment; The pressure drop generated by the adsorption of VOCs by the zeolite runner is extremely low, which can greatly reduce the power consumption; The overall system adopts pre assembly and modular design, which has a small space requirement and provides a continuous and unmanned control mode; The waste gas concentrated by the runner can meet the national emission standards; The adsorbent uses non combustible hydrophobic zeolite, which is safer to use; The disadvantage is that the one-time investment is high. The zeolite runner is essentially a concentrator, Honeycomb activated carbon production The waste gas containing organic solvent after runner treatment is divided into two parts: clean air that can be discharged directly and regeneration air containing high concentration organic solvent. The clean air that can be directly discharged can enter the spray paint air conditioning ventilation system for recycling; The concentration of high concentration VOCs is about 10 times that of the VOCs before entering the system. The concentrated gas is then incinerated at high temperature through the TNV recovery thermal incineration system (or other equipment). The heat generated by incineration is respectively used to heat the drying room and the zeolite wheel desorption. The heat is fully used to achieve the effect of energy conservation and emission reduction.
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Because there are uniform small internal pores in the molecular sieve structure, Honeycomb activated carbon Beijing When the molecular linear degree of reactants and products is close to the pore size of the crystal, the selectivity of catalytic reaction often depends on the corresponding size of the molecule and pore size. This selectivity is called shape selective catalysis. There are two mechanisms leading to shape selectivity. One is caused by the difference of diffusion coefficient of molecules participating in the reaction in the pore cavity, which is called mass transfer selectivity; The other is caused by the space limitation of the transition state of the catalytic reaction, which is called transition state selectivity. Molecular sieve has clear pore cavity distribution, extremely high internal surface area (600m2/s), good thermal stability (1000 ℃), and adjustable acid site center. The acidity of molecular sieve mainly comes from three coordinated aluminum atoms and aluminum ions (AlO)+on the framework and in the pores. The OH based acid sensitive site center on the molecular sieve HY obtained by ion exchange, and the aluminum ion outside the framework will strengthen the acid site, forming the L acid site center. Polyvalent cations such as Ca2+, Mg2+and La3+can show the acid site center after exchange. The reduction of transition metal ions such as Cu2+and Ag+can also form acid site centers. In general, the higher the Al/Si ratio, the higher the specific activity of OH group. The modification of zeolite acidity can introduce protons through direct exchange of dilute hydrochloric acid. Honeycomb activated carbon high quality This method often leads to dealumination of molecular sieve framework. So NaY will become NH4Y and then HY.
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Honeycomb zeolite molecular sieve has the crystal structure and characteristics, the surface is a solid skeleton, and the internal holes can play the role of adsorption molecules. There are channels between the holes to connect with each other, and molecules pass through the channels. Due to the crystalline nature of the pores, the pore size distribution of the molecular sieve is very uniform. Molecular sieves selectively adsorb molecules according to the size of holes in their crystals, that is, they adsorb molecules of a certain size and repel molecules of larger substances, so they are vividly called "molecular sieves". The adsorption or repulsion function of molecular sieves is affected by the molecular electricity. Synthetic zeolite has the special function of selective adsorption according to molecular size and polarity, Honeycomb activated carbon production Therefore, gas or liquid can be dried or purified, which is also the basis for molecular sieve separation. Synthetic zeolite can meet the extensive demand of industry for adsorption and selective products, Beijing Honeycomb activated carbon It is also widely used in industrial separation to synthesize zeolite molecular sieves. Advantages of UOP molecular sieve