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The main material of honeycomb zeolite adsorbent is natural zeolite. The zeolite manufacturer is an inorganic microporous material composed of sio2, al_2o_3 and alkaline metal or alkaline earth metal, Special activated carbon for catalyst carrier high quality Its inner pore volume accounts for 40-50% of the total volume, and its specific surface area is 100-500 m2/g. It is characterized by high temperature resistance, non flammability, good thermal stability and hydrothermal stability. It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and can be regenerated at high temperature. Compared with honeycomb activated carbon, its performance is about 25% of its efficiency, but it has high temperature resistance and is not easy to ignite Catalysis and environment are widely used, which is more suitable for the treatment of organic waste gas with large air volume and low concentration. Zeolite adsorbent products include microporous adsorbent and mesoporous adsorbent. Special activated carbon for catalyst carrier Direct selling (1) Microporous molecular sieves with molecular pore size below 2 nm and mesoporous molecular sieves with molecular pore size between 2-50 nm (50 nm The above are macroporous molecular sieves), mesoporous molecular sieves have high specific surface area, regular and orderly pore structure, narrow pore size distribution, continuous and adjustable pore size and other characteristics, which make it play an important role in the adsorption, separation and catalytic reaction of macromolecules that are difficult for many microporous molecular sieves to complete. (2) Therefore, molecular sieve materials with different properties and pore sizes shall be configured according to the different components of organic waste gas during selection, so as to achieve targeted organic waste gas treatment, meet the design requirements and emission standards.
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With the continuous deepening of research, honeycomb zeolite molecular sieve has gradually moved from laboratory to industrial practical application. Due to its powerful performance, it can be integrated with the reactor, Zhejiang Special activated carbon for catalyst carrier In membrane catalytic reaction, the reaction is coupled with separation. At present, the application fields of zeolite membrane are pervaporation, gas separation and membrane reactor. It is the needs of human practical activities and the development of application fields that constantly promote the development of zeolite molecular sieves. From natural zeolite to synthetic zeolite, from low silica zeolite to high silica zeolite; From silicoaluminium molecular sieve to aluminophosphate molecular sieve; From super micropore to mesoporous material; Special activated carbon for catalyst carrier high quality The development from inorganic porous frameworks to MOFs, as well as the recent emergence of macroporous materials, has effectively improved the yield, reduced the synthesis cost and environmental pollution.
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The zeolite wheel adsorption purification device is a gas purification device that can continuously perform adsorption and desorption operations. Special activated carbon for catalyst carrier high quality The two sides of the zeolite runner are divided into three areas by special sealing devices: adsorption area, desorption (regeneration) area and cooling area. The working process of the system is as follows: the zeolite runner rotates continuously at a low speed and circulates through the adsorption area, desorption (regeneration) area and cooling area; When the exhaust gas with low concentration and large air volume continuously passes through the adsorption area of the runner, VOCs in the exhaust gas are adsorbed by the zeolite of the runner, and the gas purified by adsorption is directly discharged; The organic solvent adsorbed by the wheel is sent to the desorption (regeneration) area along with the rotation of the wheel, and then continuously passes through the desorption area with small amount of hot air, high quality Zhejiang VOCs adsorbed on the runner are thermally desorbed in the desorption area to achieve regeneration, and VOCs waste gas is discharged with hot air; After the runner is transferred to the cooling area for cooling, it can be re adsorbed. With the continuous rotation of the runner, adsorption, desorption and cooling cycles are carried out to ensure the continuous and stable operation of waste gas treatment
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Special activated carbon for catalyst carrier high quality With the deepening of research, zeolite molecular sieves have gradually moved from laboratory to industrial application. Due to its powerful performance, it can be integrated with the reactor. In membrane catalytic reaction, reaction and separation are coupled. At present, the application fields of zeolite membrane are pervaporation, gas separation and membrane reactor. It is the needs of human practical activities and the development of application fields that constantly promote the development of zeolite molecular sieves. From natural zeolite to synthetic zeolite, from low silica zeolite to high silica zeolite; From silicoaluminium molecular sieve to aluminophosphate molecular sieve; From super micropore to mesoporous material; From inorganic porous frameworks to MOFs, and recently emerging macroporous materials, the yield has been effectively improved, and the synthesis cost and environmental pollution have been reduced
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Special activated carbon for catalyst carrier Zhejiang Because the aluminum oxide tetrahedron of zeolite has a negative charge, and the skeleton hole contains cations, a strong electric field is formed around the cations. Therefore, the adsorption force of zeolite not only has a strong dispersion force, but also has a large electrostatic force. It is precisely because of this electrostatic relationship that zeolites have preferential selective adsorption on polar, unsaturated and polarizable molecules. It can strongly adsorb molecules containing polar groups such as hydroxyl ion, ammonium ion and other polarizable groups, especially water, which can form hydrogen bonds with aluminum silicon skeleton, so zeolite has strong water absorption. It can still adsorb even under low relative humidity and concentration, and its water absorption is higher than that of silica gel and activated alumina. The main material of honeycomb zeolite adsorbent is natural zeolite. The manufacturer of zeolite is composed of silica Inorganic microporous material composed of al_2o_3 and alkaline metal or alkaline earth metal, with inner pore volume accounting for 40-50% of the total volume and specific surface area of 100-500 m2/g, is characterized by high temperature resistance, non flammability, good thermal stability and hydrothermal stability. It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and can be regenerated at high temperature. Compared with honeycomb activated carbon, its performance is about 25% of its efficiency, However, it is widely used in the fields of adsorption, separation, catalysis and environment due to its high temperature resistance and difficult ignition. It is more suitable for the treatment of organic waste gas with large air volume and low concentration.
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Because there are uniform small internal pores in the molecular sieve structure, Special activated carbon for catalyst carrier Zhejiang When the molecular linear degree of reactants and products is close to the pore size of the crystal, the selectivity of catalytic reaction often depends on the corresponding size of the molecule and pore size. This selectivity is called shape selective catalysis. There are two mechanisms leading to shape selectivity. One is caused by the difference of diffusion coefficient of molecules participating in the reaction in the pore cavity, which is called mass transfer selectivity; The other is caused by the space limitation of the transition state of the catalytic reaction, which is called transition state selectivity. Molecular sieve has clear pore cavity distribution, extremely high internal surface area (600m2/s), good thermal stability (1000 ℃), and adjustable acid site center. The acidity of molecular sieve mainly comes from three coordinated aluminum atoms and aluminum ions (AlO)+on the framework and in the pores. The OH based acid sensitive site center on the molecular sieve HY obtained by ion exchange, and the aluminum ion outside the framework will strengthen the acid site, forming the L acid site center. Polyvalent cations such as Ca2+, Mg2+and La3+can show the acid site center after exchange. The reduction of transition metal ions such as Cu2+and Ag+can also form acid site centers. In general, the higher the Al/Si ratio, the higher the specific activity of OH group. The modification of zeolite acidity can introduce protons through direct exchange of dilute hydrochloric acid. Special activated carbon for catalyst carrier high quality This method often leads to dealumination of molecular sieve framework. So NaY will become NH4Y and then HY.