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Fuzhou high-quality honeycomb zeolite molecular sieve manufacturer

2020-07-19
 Fuzhou high-quality honeycomb zeolite molecular sieve manufacturer

Honeycomb zeolite molecular sieve high quality Technical performance and characteristics: simple structure, convenient maintenance and long service life; High absorption and desorption efficiency, so that VOCss waste gas with high air volume and low concentration can be converted into low air volume and high concentration waste gas, reducing the cost of back-end final treatment equipment; The pressure drop generated by the adsorption of VOCs by the zeolite runner is extremely low, which can greatly reduce the power consumption; The overall system adopts pre assembly and modular design, which has a small space requirement and provides a continuous and unmanned control mode; The waste gas concentrated by the runner can meet the national emission standards; The adsorbent uses non combustible hydrophobic zeolite, which is safer to use; The disadvantage is that the one-time investment is high. The zeolite runner is essentially a concentrator, Honeycomb zeolite molecular sieve manufactor The waste gas containing organic solvent after runner treatment is divided into two parts: clean air that can be discharged directly and regeneration air containing high concentration organic solvent. The clean air that can be directly discharged can enter the spray paint air conditioning ventilation system for recycling; The concentration of high concentration VOCs is about 10 times that of the VOCs before entering the system. The concentrated gas is then incinerated at high temperature through the TNV recovery thermal incineration system (or other equipment). The heat generated by incineration is respectively used to heat the drying room and the zeolite wheel desorption. The heat is fully used to achieve the effect of energy conservation and emission reduction.

 Fuzhou high-quality honeycomb zeolite molecular sieve manufacturer

With the continuous deepening of research, honeycomb zeolite molecular sieve has gradually moved from laboratory to industrial practical application. Due to its powerful performance, it can be integrated with the reactor, Fuzhou Honeycomb zeolite molecular sieve In membrane catalytic reaction, the reaction is coupled with separation. At present, the application fields of zeolite membrane are pervaporation, gas separation and membrane reactor. It is the needs of human practical activities and the development of application fields that constantly promote the development of zeolite molecular sieves. From natural zeolite to synthetic zeolite, from low silica zeolite to high silica zeolite; From silicoaluminium molecular sieve to aluminophosphate molecular sieve; From super micropore to mesoporous material; Honeycomb zeolite molecular sieve high quality The development from inorganic porous frameworks to MOFs, as well as the recent emergence of macroporous materials, has effectively improved the yield, reduced the synthesis cost and environmental pollution.

 Fuzhou high-quality honeycomb zeolite molecular sieve manufacturer

The adsorption capacity of zeolite for organic pollutants mainly depends on the polar size and molecular diameter of organic molecules. Small molecules are easier to be adsorbed than large molecules, while polar molecules are easier to be adsorbed than non-polar ones. Different substances (such as organic molecules, metal ions and water molecules) exist in water, Honeycomb zeolite molecular sieve Fuzhou Their polarity and molecular size are different, and competition will occur during adsorption. The main material of honeycomb zeolite adsorbent is natural zeolite. The manufacturer of zeolite is composed of silica Inorganic microporous material composed of al_2o_3 and alkaline metal or alkaline earth metal, with inner pore volume accounting for 40-50% of the total volume and specific surface area of 100-500 m2/g, is characterized by high temperature resistance, non flammability, good thermal stability and hydrothermal stability. It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and can be regenerated at high temperature. Compared with honeycomb activated carbon, its performance is about 25% of its efficiency, Honeycomb zeolite molecular sieve manufactor However, it is widely used in the fields of adsorption, separation, catalysis and environment due to its high temperature resistance and difficult ignition. It is more suitable for the treatment of organic waste gas with large air volume and low concentration.

 Fuzhou high-quality honeycomb zeolite molecular sieve manufacturer

High silica zeolite type molecular sieves, this kind of zeolite has a series, and ZSM-5 is widely used, with ZSM-8 and ZSM-11 having the same structure; The other group is ZSM-21, ZSM-35 and ZSM-38. ZSM-5 is often called high silica zeolite, with the Si/Al ratio up to 50 and ZSM-8 up to 100. This group of molecular sieves also shows hydrophobic characteristics. Honeycomb zeolite molecular sieve manufactor Their structural units are similar to those of mordenite, consisting of pairs of five membered rings, with no cage like cavities and only channels. ZSM-5 has two sets of cross channels, one is straight through, the other is zigzag perpendicular to each other, both formed by ten yuan rings. The channel is oval and its window diameter is (0.55-0.60) nm. Honeycomb zeolite molecular sieve high quality Zeolites belonging to the high silicon group also have silicalite-1 of all silicon type, which has the same structure as ZSM-5, and silicalite-2 is the same as ZSM-11.

 Fuzhou high-quality honeycomb zeolite molecular sieve manufacturer

Because there are uniform small internal pores in the molecular sieve structure, Honeycomb zeolite molecular sieve Fuzhou When the molecular linear degree of reactants and products is close to the pore size of the crystal, the selectivity of catalytic reaction often depends on the corresponding size of the molecule and pore size. This selectivity is called shape selective catalysis. There are two mechanisms leading to shape selectivity. One is caused by the difference of diffusion coefficient of molecules participating in the reaction in the pore cavity, which is called mass transfer selectivity; The other is caused by the space limitation of the transition state of the catalytic reaction, which is called transition state selectivity. Molecular sieve has clear pore cavity distribution, extremely high internal surface area (600m2/s), good thermal stability (1000 ℃), and adjustable acid site center. The acidity of molecular sieve mainly comes from three coordinated aluminum atoms and aluminum ions (AlO)+on the framework and in the pores. The OH based acid sensitive site center on the molecular sieve HY obtained by ion exchange, and the aluminum ion outside the framework will strengthen the acid site, forming the L acid site center. Polyvalent cations such as Ca2+, Mg2+and La3+can show the acid site center after exchange. The reduction of transition metal ions such as Cu2+and Ag+can also form acid site centers. In general, the higher the Al/Si ratio, the higher the specific activity of OH group. The modification of zeolite acidity can introduce protons through direct exchange of dilute hydrochloric acid. Honeycomb zeolite molecular sieve high quality This method often leads to dealumination of molecular sieve framework. So NaY will become NH4Y and then HY.

 Fuzhou high-quality honeycomb zeolite molecular sieve manufacturer

The holes and channels inside the zeolite crystal are uniform and fixed in size, and the diameter of the holes is generally 6~15A. Honeycomb zeolite molecular sieve Fuzhou Only molecules with smaller diameter can enter the cavity through the zeolite channel and be adsorbed, while large molecules cannot enter the cavity and be adsorbed. Zeolite is also called molecular sieve because of its selective adsorption performance. However, silica gel, activated carbon and other adsorbents have no selective adsorption and screening performance due to their non uniformly fixed pore sizes and large changes. Shunyi zeolite filter material price. Because the silicon (aluminum) oxygen tetrahedron of natural zeolite crystal has many holes and channels, which occupy cations and water molecules. When some other goods are completely dehydrated after baking, the crystal skeleton is not damaged, but forms large holes on the inner surface, which can absorb and store a large number of molecules, so it has the characteristics of large adsorption capacity and high selectivity. Honeycomb zeolite molecular sieve high quality In different zeolite minerals, the proportion of silicon and aluminum is different, and the different proportion will cause some characteristics of zeolite changes, such as ion exchange and acid resistance.