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Columnar activated carbon Chongqing There are cavities and channels in the crystal structure of zeolite with large adsorption capacity, whose volume accounts for more than 50% of the total volume of zeolite crystals. Moreover, the micropores of zeolite are evenly distributed, and the pore size is small, which is equivalent to the molecular size of general substances. The internal surface area of zeolite crystals can reach more than 1000 square meters. Therefore, the adsorption capacity of zeolite is particularly large. The holes and channels inside the highly selective zeolite crystal are uniform and fixed in size, and the diameter of the holes is generally 6~15A. Columnar activated carbon Direct selling Only molecules with smaller diameter can enter the cavity through the zeolite channel and be adsorbed, while large molecules cannot enter the cavity and be adsorbed. Zeolite is also called molecular sieve because of its selective adsorption performance. However, silica gel, activated carbon and other adsorbents have no selective adsorption and screening performance due to their non uniformly fixed pore sizes and large changes. Price of Shunyi zeolite filter material
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The main material of honeycomb zeolite molecular sieve is natural zeolite, which is an inorganic microporous material composed of SiO2, Al2O3 and alkaline metal or alkaline earth metal. Its inner pore volume accounts for 40-50% of the total volume, and its specific surface area is 300-1000 m2/g, which has the characteristics of high temperature resistance, non flammability, good thermal stability and hydrothermal stability, Columnar activated carbon Chongqing It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and can be regenerated at high temperature. Its efficiency is 40% higher than that of similar activated carbon. It is widely used in the fields of adsorption, separation, catalysis and environment, and is more suitable for the treatment of organic waste gas with large air volume and low concentration. Columnar activated carbon high quality The adsorption material has a stable ozone decomposition ability, which significantly improves the decomposition efficiency of VOCs. The adsorption material first forms a special structural effect through the combination design of silver and manganese, which can decompose ozone into active oxygen atoms, and then react with VOCs molecules to form carbon dioxide and water.
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The main material of honeycomb zeolite adsorbent is natural zeolite. The zeolite manufacturer is an inorganic microporous material composed of sio2, al_2o_3 and alkaline metal or alkaline earth metal, Columnar activated carbon high quality Its inner pore volume accounts for 40-50% of the total volume, and its specific surface area is 100-500 m2/g. It is characterized by high temperature resistance, non flammability, good thermal stability and hydrothermal stability. It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and can be regenerated at high temperature. Compared with honeycomb activated carbon, its performance is about 25% of its efficiency, but it has high temperature resistance and is not easy to ignite Catalysis and environment are widely used, which is more suitable for the treatment of organic waste gas with large air volume and low concentration. Zeolite adsorbent products include microporous adsorbent and mesoporous adsorbent. Columnar activated carbon Direct selling (1) Microporous molecular sieves with molecular apertures below 2 nm, mesoporous molecular sieves with molecular apertures above 50 nm (macroporous molecular sieves with molecular apertures above 50 nm), mesoporous molecular sieves have high specific surface area, regular and orderly pore structure, narrow pore size distribution, continuous and adjustable pore size and other characteristics, which make it difficult to complete the adsorption and separation of macromolecules in many microporous molecular sieves, And catalytic reaction. (2) Therefore, molecular sieve materials with different properties and pore sizes shall be configured according to the different components of organic waste gas during selection, so as to achieve targeted organic waste gas treatment, meet the design requirements and emission standards.
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Columnar activated carbon high quality With the deepening of research, zeolite molecular sieves have gradually moved from laboratory to industrial application. Due to its powerful performance, it can be integrated with the reactor. In membrane catalytic reaction, reaction and separation are coupled. At present, the application fields of zeolite membrane are pervaporation, gas separation and membrane reactor. It is the needs of human practical activities and the development of application fields that constantly promote the development of zeolite molecular sieves. From natural zeolite to synthetic zeolite, from low silica zeolite to high silica zeolite; From silicoaluminium molecular sieve to aluminophosphate molecular sieve; From super micropore to mesoporous material; From inorganic porous frameworks to MOFs, and recently emerging macroporous materials, the yield has been effectively improved, and the synthesis cost and environmental pollution have been reduced
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Molecular sieve has clear pore cavity distribution, extremely high internal surface area (600m2/s), good thermal stability (1000 ℃), and adjustable acid site center. The acidity of molecular sieve mainly comes from three coordinated aluminum atoms and aluminum ions (AlO)+on the framework and in the pores. OH based acid sensitive site center on molecular sieve HY obtained by ion exchange, Columnar activated carbon Chongqing The aluminum ions outside the framework will strengthen the acid site and form the L acid site center. Polyvalent cations such as Ca2+, Mg2+and La3+can show the acid site center after exchange. The reduction of transition metal ions such as Cu2+and Ag+can also form acid site centers. In general, the higher the Al/Si ratio, the higher the specific activity of OH group. The modification of zeolite acidity can introduce protons through direct exchange of dilute hydrochloric acid. This method often leads to dealumination of molecular sieve framework. So NaY will become NH4Y and then HY. Because there are uniform small internal pores in the molecular sieve structure, when the molecular linearity of reactants and products is close to the pore size of the crystal, the selectivity of the catalytic reaction often depends on the corresponding size of the molecule and pore size. Columnar activated carbon high quality This selectivity is called shape selective catalysis. There are two mechanisms leading to shape selectivity. One is caused by the difference of diffusion coefficient of molecules participating in the reaction in the pore cavity, which is called mass transfer selectivity; The other is caused by the space limitation of the transition state of the catalytic reaction, which is called transition state selectivity.
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The zeolite wheel adsorption purification device is a gas purification device that can continuously perform adsorption and desorption operations. Columnar activated carbon high quality The two sides of the zeolite runner are divided into three areas by special sealing devices: adsorption area, desorption (regeneration) area and cooling area. The working process of the system is as follows: the zeolite runner rotates continuously at a low speed and circulates through the adsorption area, desorption (regeneration) area and cooling area; When the exhaust gas with low concentration and large air volume continuously passes through the adsorption area of the runner, VOCs in the exhaust gas are adsorbed by the zeolite of the runner, and the gas purified by adsorption is directly discharged; The organic solvent adsorbed by the wheel is sent to the desorption (regeneration) area along with the rotation of the wheel, and then continuously passes through the desorption area with small amount of hot air, high quality Chongqing VOCs adsorbed on the runner are thermally desorbed in the desorption area to achieve regeneration, and VOCs waste gas is discharged with hot air; After the runner is transferred to the cooling area for cooling, it can be re adsorbed. With the continuous rotation of the runner, adsorption, desorption and cooling cycles are carried out to ensure the continuous and stable operation of waste gas treatment