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Liquid phase honeycomb activated carbon high quality Due to its large pore size, mesoporous materials have become a good carrier for molecular reaction with large size. However, the pore wall of mesoporous materials is amorphous, so their hydrothermal stability and thermal stability cannot meet the harsh conditions required for petrochemical applications. Because there are metal ions with low electricity price and large ion radius and water in the combined state, water molecules are continuously lost after heating, but the crystal skeleton structure remains unchanged, forming many cavities with the same size. The cavities are connected by many micropores with the same diameter. These tiny holes have uniform diameters, which can adsorb molecules smaller than the diameter of the hole into the interior of the hole, By excluding molecules larger than pores, molecules with different shapes, diameters, polarities, boiling points and saturation levels can be separated, Liquid phase honeycomb activated carbon production It has the function of "screening" molecules, so it is called molecular sieve. At present, molecular sieves are widely used in metallurgy, chemical industry, electronics, petrochemical industry, natural gas and other industries.
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Liquid phase honeycomb activated carbon high quality The highly effective selective adsorption is due to the fact that the alumina tetrahedron of zeolite has a negative charge, while the skeleton hole contains cations, which forms a strong electric field around the cations. Therefore, the adsorption force of zeolite not only has a strong dispersion force, but also has a large electrostatic force. It is precisely because of this electrostatic relationship that zeolites have preferential selective adsorption on polar, unsaturated and polarizable molecules. It can strongly adsorb molecules containing polar groups such as hydroxyl ion, ammonium ion and other polarizable groups, especially water, which can form hydrogen bonds with aluminum silicon skeleton, so zeolite has strong water absorption. It can still adsorb even under low relative humidity and concentration, and its water absorption is higher than that of silica gel and activated alumina. The adsorption capacity of zeolite for organic pollutants mainly depends on the polar size and molecular diameter of organic molecules. Small molecules are easier to be adsorbed than large molecules, while polar molecules are easier to be adsorbed than non-polar ones. Different substances (such as organic molecules, metal ions and water molecules) exist in water, Liquid phase honeycomb activated carbon production Their polarity and molecular size are different, and competition will occur during adsorption.
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Because there are uniform small internal pores in the molecular sieve structure, Liquid phase honeycomb activated carbon Jiangxi When the molecular linear degree of reactants and products is close to the pore size of the crystal, the selectivity of catalytic reaction often depends on the corresponding size of the molecule and pore size. This selectivity is called shape selective catalysis. There are two mechanisms leading to shape selectivity. One is caused by the difference of diffusion coefficient of molecules participating in the reaction in the pore cavity, which is called mass transfer selectivity; The other is caused by the space limitation of the transition state of the catalytic reaction, which is called transition state selectivity. Molecular sieve has clear pore cavity distribution, extremely high internal surface area (600m2/s), good thermal stability (1000 ℃), and adjustable acid site center. The acidity of molecular sieve mainly comes from three coordinated aluminum atoms and aluminum ions (AlO)+on the framework and in the pores. The OH based acid sensitive site center on the molecular sieve HY obtained by ion exchange, and the aluminum ion outside the framework will strengthen the acid site, forming the L acid site center. Polyvalent cations such as Ca2+, Mg2+and La3+can show the acid site center after exchange. The reduction of transition metal ions such as Cu2+and Ag+can also form acid site centers. In general, the higher the Al/Si ratio, the higher the specific activity of OH group. The modification of zeolite acidity can introduce protons through direct exchange of dilute hydrochloric acid. Liquid phase honeycomb activated carbon high quality This method often leads to dealumination of molecular sieve framework. So NaY will become NH4Y and then HY.
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Molecular sieve has clear pore cavity distribution, extremely high internal surface area (600m2/s), good thermal stability (1000 ℃), and adjustable acid site center. The acidity of molecular sieve mainly comes from three coordinated aluminum atoms and aluminum ions (AlO)+on the framework and in the pores. OH based acid sensitive site center on molecular sieve HY obtained by ion exchange, Liquid phase honeycomb activated carbon Jiangxi The aluminum ions outside the framework will strengthen the acid site and form the L acid site center. Polyvalent cations such as Ca2+, Mg2+and La3+can show the acid site center after exchange. The reduction of transition metal ions such as Cu2+and Ag+can also form acid site centers. In general, the higher the Al/Si ratio, the higher the specific activity of OH group. The modification of zeolite acidity can introduce protons through direct exchange of dilute hydrochloric acid. This method often leads to dealumination of molecular sieve framework. So NaY will become NH4Y and then HY. Because there are uniform small internal pores in the structure of molecular sieves, when the molecular linearity of reactants and products is close to the pore size in the crystal, the selectivity of catalytic reaction often depends on the corresponding size of molecules and pore size. Liquid phase honeycomb activated carbon high quality This selectivity is called shape selective catalysis. There are two mechanisms leading to shape selectivity. One is caused by the difference of diffusion coefficient of molecules participating in the reaction in the pore cavity, which is called mass transfer selectivity; The other is caused by the space limitation of the transition state of the catalytic reaction, which is called transition state selectivity.
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Liquid phase honeycomb activated carbon Jiangxi There are cavities and channels in the crystal structure of zeolite with large adsorption capacity, whose volume accounts for more than 50% of the total volume of zeolite crystals. Moreover, the micropores of zeolite are evenly distributed, and the pore size is small, which is equivalent to the molecular size of general substances. The internal surface area of zeolite crystals can reach more than 1000 square meters. Therefore, the adsorption capacity of zeolite is particularly large. The holes and channels inside the highly selective zeolite crystal are uniform and fixed in size, and the diameter of the holes is generally 6~15A. Liquid phase honeycomb activated carbon production Only molecules with smaller diameter can enter the cavity through the zeolite channel and be adsorbed, while large molecules cannot enter the cavity and be adsorbed. Zeolite is also called molecular sieve because of its selective adsorption performance. However, silica gel, activated carbon and other adsorbents have no selective adsorption and screening performance due to their non uniformly fixed pore sizes and large changes. Price of Shunyi zeolite filter material