Zeolite molecular sieve is a kind of excellent adsorbent, which is widely used in the production of basic organic chemical industry and petrochemical industry, as well as in the treatment of harmful gases nox、co、co2,nh3,ccl4、 Purification of water vapor and gaseous hydrocarbon waste gas; As well as air purification and deodorization in biochemical industry, paint industry, underground places, leather factories and animal breeding places; Adsorption of flue gas odor, removal of mercury vapor, etc. The factors affecting the purification efficiency of honeycomb zeolite molecular sieves are absorption and desorption. If the waste gas adsorbed on the runner cannot be completely desorbed, the runner will become saturated after a long time, which will affect the adsorption efficiency of the zeolite runner, Activated carbon fiber high quality The service life of zeolite will be directly affected over time.
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The adsorption capacity of zeolite for organic pollutants mainly depends on the polar size and molecular diameter of organic molecules. Small molecules are easier to be adsorbed than large molecules, while polar molecules are easier to be adsorbed than non-polar ones. Different substances (such as organic molecules, metal ions and water molecules) exist in water, Activated carbon fiber Zhejiang Their polarity and molecular size are different, and competition will occur during adsorption. The main material of honeycomb zeolite adsorbent is natural zeolite. The manufacturer of zeolite is composed of silica Inorganic microporous material composed of al_2o_3 and alkaline metal or alkaline earth metal, with inner pore volume accounting for 40-50% of the total volume and specific surface area of 100-500 m2/g, is characterized by high temperature resistance, non flammability, good thermal stability and hydrothermal stability. It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and can be regenerated at high temperature. Compared with honeycomb activated carbon, its performance is about 25% of its efficiency, Activated carbon fiber production However, it is widely used in the fields of adsorption, separation, catalysis and environment due to its high temperature resistance and difficult ignition. It is more suitable for the treatment of organic waste gas with large air volume and low concentration.
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Because there are uniform small internal pores in the molecular sieve structure, Activated carbon fiber Zhejiang When the molecular linear degree of reactants and products is close to the pore size of the crystal, the selectivity of catalytic reaction often depends on the corresponding size of the molecule and pore size. This selectivity is called shape selective catalysis. There are two mechanisms leading to shape selectivity. One is caused by the difference of diffusion coefficient of molecules participating in the reaction in the pore cavity, which is called mass transfer selectivity; The other is caused by the space limitation of the transition state of the catalytic reaction, which is called transition state selectivity. Molecular sieve has clear pore cavity distribution, extremely high internal surface area (600m2/s), good thermal stability (1000 ℃), and adjustable acid site center. The acidity of molecular sieve mainly comes from three coordinated aluminum atoms and aluminum ions (AlO)+on the framework and in the pores. The OH based acid sensitive site center on the molecular sieve HY obtained by ion exchange, and the aluminum ion outside the framework will strengthen the acid site, forming the L acid site center. Polyvalent cations such as Ca2+, Mg2+and La3+can show the acid site center after exchange. The reduction of transition metal ions such as Cu2+and Ag+can also form acid site centers. In general, the higher the Al/Si ratio, the higher the specific activity of OH group. The modification of zeolite acidity can introduce protons through direct exchange of dilute hydrochloric acid. Activated carbon fiber high quality This method often leads to dealumination of molecular sieve framework. So NaY will become NH4Y and then HY.
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The holes and channels inside the zeolite crystal are uniform and fixed in size, and the diameter of the holes is generally 6~15A. Activated carbon fiber Zhejiang Only molecules with smaller diameter can enter the cavity through the zeolite channel and be adsorbed, while large molecules cannot enter the cavity and be adsorbed. Zeolite is also called molecular sieve because of its selective adsorption performance. However, silica gel, activated carbon and other adsorbents have no selective adsorption and screening performance due to their non uniformly fixed pore sizes and large changes. Shunyi zeolite filter material price. Because the silicon (aluminum) oxygen tetrahedron of natural zeolite crystal has many holes and channels, which occupy cations and water molecules. When some other goods are completely dehydrated after baking, the crystal skeleton is not damaged, but forms large holes on the inner surface, which can absorb and store a large number of molecules, so it has the characteristics of large adsorption capacity and high selectivity. Activated carbon fiber high quality In different zeolite minerals, the proportion of silicon and aluminum is different, and the different proportion will cause some characteristics of zeolite changes, such as ion exchange and acid resistance.
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Honeycomb zeolite molecular sieve has the crystal structure and characteristics, the surface is a solid skeleton, and the internal holes can play the role of adsorption molecules. There are channels between the holes to connect with each other, and molecules pass through the channels. Due to the crystalline nature of the pores, the pore size distribution of the molecular sieve is very uniform. Molecular sieves selectively adsorb molecules according to the size of holes in their crystals, that is, they adsorb molecules of a certain size and repel molecules of larger substances, so they are vividly called "molecular sieves". The adsorption or repulsion function of molecular sieves is affected by the molecular electricity. Synthetic zeolite has the special function of selective adsorption according to molecular size and polarity, Activated carbon fiber production Therefore, gas or liquid can be dried or purified, which is also the basis for molecular sieve separation. Synthetic zeolite can meet the extensive demand of industry for adsorption and selective products, Zhejiang Activated carbon fiber It is also widely used in industrial separation to synthesize zeolite molecular sieves. Advantages of UOP molecular sieve
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Activated carbon fiber high quality In addition to physical adsorption, chemical reaction also often occurs on the surface of zeolite, which contains a small amount of chemical combination, oxygen and hydrogen in the form of functional groups. These surfaces contain oxides or complexes that can react with the adsorbed substances, so that they can combine with the adsorbed substances and aggregate to the interior and surface of zeolite. Activated carbon fiber Zhejiang The main material of honeycomb zeolite adsorbent is natural zeolite. The manufacturer of zeolite is composed of silica Inorganic microporous material composed of al_2o_3 and alkaline metal or alkaline earth metal, with inner pore volume accounting for 40-50% of the total volume and specific surface area of 100-500 m2/g, is characterized by high temperature resistance, non flammability, good thermal stability and hydrothermal stability. It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and can be regenerated at high temperature. Compared with honeycomb activated carbon, its performance is about 25% of its efficiency, However, it is widely used in the fields of adsorption, separation, catalysis and environment due to its high temperature resistance and difficult ignition. It is more suitable for the treatment of organic waste gas with large air volume and low concentration.