Zeolite molecular sieve is a kind of excellent adsorbent, which is widely used in the production of basic organic chemical industry and petrochemical industry, as well as in the treatment of harmful gases nox、co、co2,nh3,ccl4、 Purification of water vapor and gaseous hydrocarbon waste gas; As well as air purification and deodorization in biochemical industry, paint industry, underground places, leather factories and animal breeding places; Adsorption of flue gas odor, removal of mercury vapor, etc. The factors affecting the purification efficiency of honeycomb zeolite molecular sieves are absorption and desorption. If the waste gas adsorbed on the runner cannot be completely desorbed, the runner will become saturated after a long time, which will affect the adsorption efficiency of the zeolite runner, Zeolite honeycomb molecular sieve major The service life of zeolite will be directly affected over time.
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Molecular sieve has clear pore cavity distribution, extremely high internal surface area (600m2/s), good thermal stability (1000 ℃), and adjustable acid site center. The acidity of molecular sieve mainly comes from three coordinated aluminum atoms and aluminum ions (AlO)+on the framework and in the pores. OH based acid sensitive site center on molecular sieve HY obtained by ion exchange, Zeolite honeycomb molecular sieve Fujian The aluminum ions outside the framework will strengthen the acid site and form the L acid site center. Polyvalent cations such as Ca2+, Mg2+and La3+can show the acid site center after exchange. The reduction of transition metal ions such as Cu2+and Ag+can also form acid site centers. In general, the higher the Al/Si ratio, the higher the specific activity of OH group. The modification of zeolite acidity can introduce protons through direct exchange of dilute hydrochloric acid. This method often leads to dealumination of molecular sieve framework. So NaY will become NH4Y and then HY. Because there are uniform small internal pores in the molecular sieve structure, when the molecular linearity of reactants and products is close to the pore size of the crystal, the selectivity of the catalytic reaction often depends on the corresponding size of the molecule and pore size. Zeolite honeycomb molecular sieve major This selectivity is called shape selective catalysis. There are two mechanisms leading to shape selectivity. One is caused by the difference of diffusion coefficient of molecules participating in the reaction in the pore cavity, which is called mass transfer selectivity; The other is caused by the space limitation of the transition state of the catalytic reaction, which is called transition state selectivity.
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Zeolite molecular sieves have the following potential applications. Zeolite honeycomb molecular sieve manufactor (1) Due to the high whiteness of molecular sieves, the optical properties of paper can be improved. (2) It can improve the loose thickness and printability of the paper. (3) Molecular sieves can be used to prepare special papers such as gas filter paper, rust proof paper and photocatalysis paper due to their open structure. (4) It can be used for low weight newsprint and book paper, and can effectively avoid ink penetration. (5) Its ion exchange performance can avoid resin and filler deposition. Zeolite honeycomb molecular sieve major (6) It can be used for phenolic paper laminate to improve its corrosion resistance in humid environment. Phenolic paper laminates used as insulators in printed circuit boards and integrated circuits will be affected by electrolytic corrosion when exposed to high humidity. (7) It is mixed with titanium dioxide (TiO2) filler to produce high-quality white paper.
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Zeolite honeycomb molecular sieve major In the process of removing impurities in the liquid and gas phases, the porous structure of zeolite provides a large amount of specific surface area, which makes it very easy to absorb and collect impurities. Due to the mutual adsorption of molecules, a large number of molecules on the pore wall of zeolite can generate strong gravity, just like magnetic force, So as to achieve the purpose of attracting impurities in the medium to the aperture. The main material of honeycomb zeolite adsorbent is natural zeolite. The manufacturer of zeolite is composed of silica Inorganic microporous material composed of al_2o_3 and alkaline metal or alkaline earth metal, with inner pore volume accounting for 40-50% of the total volume and specific surface area of 100-500 m2/g, is characterized by high temperature resistance, non flammability, good thermal stability and hydrothermal stability. It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and can be regenerated at high temperature. Compared with honeycomb activated carbon, its performance is about 25% of its efficiency, Zeolite honeycomb molecular sieve manufactor However, it is widely used in the fields of adsorption, separation, catalysis and environment due to its high temperature resistance and difficult ignition. It is more suitable for the treatment of organic waste gas with large air volume and low concentration.
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Zeolite honeycomb molecular sieve major The highly effective selective adsorption is due to the fact that the alumina tetrahedron of zeolite has a negative charge, while the skeleton hole contains cations, which forms a strong electric field around the cations. Therefore, the adsorption force of zeolite not only has a strong dispersion force, but also has a large electrostatic force. It is precisely because of this electrostatic relationship that zeolites have preferential selective adsorption on polar, unsaturated and polarizable molecules. It can strongly adsorb molecules containing polar groups such as hydroxyl ion, ammonium ion and other polarizable groups, especially water, which can form hydrogen bonds with aluminum silicon skeleton, so zeolite has strong water absorption. It can still adsorb even under low relative humidity and concentration, and its water absorption is higher than that of silica gel and activated alumina. The adsorption capacity of zeolite for organic pollutants mainly depends on the polar size and molecular diameter of organic molecules. Small molecules are easier to be adsorbed than large molecules, while polar molecules are easier to be adsorbed than non-polar ones. Different substances (such as organic molecules, metal ions and water molecules) exist in water, Zeolite honeycomb molecular sieve manufactor Their polarity and molecular size are different, and competition will occur during adsorption.
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The main material of honeycomb zeolite adsorbent is natural zeolite. The zeolite manufacturer is an inorganic microporous material composed of sio2, al_2o_3 and alkaline metal or alkaline earth metal, Zeolite honeycomb molecular sieve major Its inner pore volume accounts for 40-50% of the total volume, and its specific surface area is 100-500 m2/g. It is characterized by high temperature resistance, non flammability, good thermal stability and hydrothermal stability. It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and can be regenerated at high temperature. Compared with honeycomb activated carbon, its performance is about 25% of its efficiency, but it has high temperature resistance and is not easy to ignite Catalysis and environment are widely used, which is more suitable for the treatment of organic waste gas with large air volume and low concentration. Zeolite adsorbent products include microporous adsorbent and mesoporous adsorbent. Zeolite honeycomb molecular sieve manufactor (1) Microporous molecular sieves with molecular apertures below 2 nm, mesoporous molecular sieves with molecular apertures above 50 nm (macroporous molecular sieves with molecular apertures above 50 nm), mesoporous molecular sieves have high specific surface area, regular and orderly pore structure, narrow pore size distribution, continuous and adjustable pore size and other characteristics, which make it difficult to complete the adsorption and separation of macromolecules in many microporous molecular sieves, And catalytic reaction. (2) Therefore, molecular sieve materials with different properties and pore sizes shall be configured according to the different components of organic waste gas during selection, so as to achieve targeted organic waste gas treatment, meet the design requirements and emission standards.