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Molecular sieve has clear pore cavity distribution, extremely high internal surface area (600m2/s), good thermal stability (1000 ℃), and adjustable acid site center. The acidity of molecular sieve mainly comes from three coordinated aluminum atoms and aluminum ions (AlO)+on the framework and in the pores. OH based acid sensitive site center on molecular sieve HY obtained by ion exchange, Activated carbon filter screen Ganzhou The aluminum ions outside the framework will strengthen the acid site and form the L acid site center. Polyvalent cations such as Ca2+, Mg2+and La3+can show the acid site center after exchange. The reduction of transition metal ions such as Cu2+and Ag+can also form acid site centers. In general, the higher the Al/Si ratio, the higher the specific activity of OH group. The modification of zeolite acidity can introduce protons through direct exchange of dilute hydrochloric acid. This method often leads to dealumination of molecular sieve framework. So NaY will become NH4Y and then HY. Because there are uniform small internal pores in the molecular sieve structure, when the molecular linearity of reactants and products is close to the pore size of the crystal, the selectivity of the catalytic reaction often depends on the corresponding size of the molecule and pore size. Activated carbon filter screen high quality This selectivity is called shape selective catalysis. There are two mechanisms leading to shape selectivity. One is caused by the difference of diffusion coefficient of molecules participating in the reaction in the pore cavity, which is called mass transfer selectivity; The other is caused by the space limitation of the transition state of the catalytic reaction, which is called transition state selectivity.
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High silica zeolite type molecular sieves, this kind of zeolite has a series, and ZSM-5 is widely used, with ZSM-8 and ZSM-11 having the same structure; The other group is ZSM-21, ZSM-35 and ZSM-38. ZSM-5 is often called high silica zeolite, with the Si/Al ratio up to 50 and ZSM-8 up to 100. This group of molecular sieves also shows hydrophobic characteristics. Activated carbon filter screen production Their structural units are similar to those of mordenite, consisting of pairs of five membered rings, with no cage like cavities and only channels. ZSM-5 has two sets of cross channels, one is straight through, the other is zigzag perpendicular to each other, both formed by ten yuan rings. The channel is oval and its window diameter is (0.55-0.60) nm. Activated carbon filter screen high quality Zeolites belonging to the high silicon group also have silicalite-1 of all silicon type, which has the same structure as ZSM-5, and silicalite-2 is the same as ZSM-11.
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Activated carbon filter screen high quality Rely on its own unique void structure. The pore size of zeolite is uniform, the internal void structure is developed, the specific surface area is large, the adsorption capacity is strong, and contains a large number of invisible pore sizes. The pore size in 1g zeolite material can be expanded to the specific surface area of 500-1000m2, which is higher for special purposes. The mutual adsorption between molecules is also called "van der Waals gravity". Although molecular motion speed is affected by temperature, material and other factors, Activated carbon filter screen production But it always keeps moving in the micro environment. Due to the mutual attraction force between molecules, when a molecule is trapped in the inner pore volume of zeolite, it will lead to more molecules being absorbed until the adsorption of zeolite is saturated.
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Ganzhou Activated carbon filter screen Zeolite is a porous aluminosilicate crystal (a1uminsi1ict) with a water bearing frame structure, which exists naturally in nature and is also artificially synthesized. The ideal chemical formula of zeolite can be expressed as Mx/yA1XSiyO2 (x y) P? H2O, In the formula, M refers to alkali metals (such as Na, K, Li) and alkaline earth metals (such as Ca, Mg, Ba, Sr). The chemical composition of zeolite is generally considered to be composed of A12O3, SiO2, H2O and metal cations, of which A12O3 and SiO2 account for about 80% of the total amount of zeolite minerals. In different zeolite minerals, the proportion of silicon and aluminum is different, Activated carbon filter screen production And the different proportion of zeolite will cause some changes in zeolite characteristics, such as ion exchange and acid resistance. Because the silicon (aluminum) oxygen tetrahedron of natural zeolite crystal has many holes and channels, which occupy cations and water molecules. When some other goods are completely dehydrated after baking, the crystal skeleton is not damaged, but forms large holes on the inner surface, which can absorb and store a large number of molecules, so it has the characteristics of large adsorption capacity and high selectivity.
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The main components of zeolite are: silicon and aluminum, which have adsorption capacity and can be used as adsorbent; Zeolite runner is to use the specific pore size of zeolite to have the ability of adsorption and desorption for organic pollutants, so that VOCs waste gas with low concentration and large air volume can be concentrated and converted into low air volume and high concentration gas by the zeolite runner, which can reduce the operating cost of the back-end final treatment equipment. Activated carbon filter screen Ganzhou The characteristics of the device are suitable for treating waste gas with large flow, low concentration and various organic components. The disadvantage is high initial investment. The zeolite wheel adsorption purification device is a gas purification device that can continuously perform adsorption and desorption operations. The two sides of the zeolite runner are divided into three areas by special sealing devices: adsorption area, desorption (regeneration) area and cooling area. Activated carbon filter screen high quality The working process of the system is as follows: the zeolite runner rotates continuously at a low speed and circulates through the adsorption area, desorption (regeneration) area and cooling area; When the exhaust gas with low concentration and large air volume continuously passes through the adsorption area of the runner, VOCs in the exhaust gas are adsorbed by the zeolite of the runner, and the gas purified by adsorption is directly discharged; The organic solvent adsorbed by the wheel is sent to the desorption (regeneration) area with the rotation of the runner, and then the small amount of hot air continuously passes through the desorption area. The VOCs adsorbed on the runner are thermally desorbed in the desorption area to achieve regeneration, and the VOCs waste gas is discharged together with the hot air; After the runner is transferred to the cooling area for cooling, the adsorption can be carried out again. With the continuous rotation of the runner, the adsorption, desorption and cooling cycles are carried out to ensure the continuous and stable operation of waste gas treatment.
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Activated carbon filter screen Ganzhou Zeolite molecular sieve is a kind of excellent adsorbent, which is widely used in the production of basic organic chemical industry and petrochemical industry, as well as in the treatment of harmful gases nox、co、co2,nh3,ccl4、 Purification of water vapor and gaseous hydrocarbon waste gas; As well as air purification and deodorization in biochemical industry, paint industry, underground places, leather factories and animal breeding places; Adsorption of flue gas odor, removal of mercury vapor, etc. Strong adsorption selectivity. The pore size of molecular sieve is uniform, and it is also an ionic adsorbent. Therefore, it can selectively adsorb according to the size and polarity of molecules. It can effectively remove ethylene, propylene and acetylene from saturated hydrocarbons, which is determined by its strong polarity. Activated carbon filter screen production In addition to physical adsorption, chemical reaction also often occurs on the surface of zeolite, which contains a small amount of chemical combination, oxygen and hydrogen in the form of functional groups. These surfaces contain oxides or complexes that can react with the adsorbed substances, so that they can combine with the adsorbed substances and aggregate to the interior and surface of zeolite.