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Because there are uniform small internal pores in the molecular sieve structure, Small honeycomb activated carbon Shangrao When the molecular linear degree of reactants and products is close to the pore size of the crystal, the selectivity of catalytic reaction often depends on the corresponding size of the molecule and pore size. This selectivity is called shape selective catalysis. There are two mechanisms leading to shape selectivity. One is caused by the difference of diffusion coefficient of molecules participating in the reaction in the pore cavity, which is called mass transfer selectivity; The other is caused by the space limitation of the transition state of the catalytic reaction, which is called transition state selectivity. Molecular sieve has clear pore cavity distribution, extremely high internal surface area (600m2/s), good thermal stability (1000 ℃), and adjustable acid site center. The acidity of molecular sieve mainly comes from three coordinated aluminum atoms and aluminum ions (AlO)+on the framework and in the pores. The OH based acid sensitive site center on the molecular sieve HY obtained by ion exchange, and the aluminum ion outside the framework will strengthen the acid site, forming the L acid site center. Polyvalent cations such as Ca2+, Mg2+and La3+can show the acid site center after exchange. The reduction of transition metal ions such as Cu2+and Ag+can also form acid site centers. In general, the higher the Al/Si ratio, the higher the specific activity of OH group. The modification of zeolite acidity can introduce protons through direct exchange of dilute hydrochloric acid. Small honeycomb activated carbon high quality This method often leads to dealumination of molecular sieve framework. So NaY will become NH4Y and then HY.
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The zeolite runner device is essentially a concentrator. The waste gas containing organic solvent after treatment by the runner is divided into two parts: clean air that can be discharged directly and regeneration air containing high concentration organic solvent. Small honeycomb activated carbon Shangrao The clean air that can be directly discharged can enter the spray paint air conditioning ventilation system for recycling; The concentration of high concentration VOCs is about 10 times that of the VOCs before entering the system. The concentrated gas is then incinerated at high temperature through the TNV recovery thermal incineration system (or other equipment). The heat generated by incineration is respectively used to heat the drying room and the zeolite wheel desorption. The heat is fully used to achieve the effect of energy conservation and emission reduction. Technical performance and characteristics: simple structure, convenient maintenance and long service life; High absorption and desorption efficiency, so that VOCss waste gas with high air volume and low concentration can be converted into low air volume and high concentration waste gas, reducing the cost of back-end final treatment equipment; The pressure drop generated by the adsorption of VOCs by the zeolite runner is extremely low, which can greatly reduce the power consumption; The overall system adopts pre assembly and modular design, which has a small space requirement and provides a continuous and unmanned control mode; Waste gas concentrated by runner, Small honeycomb activated carbon Direct selling It can meet the national emission standards; The adsorbent uses non combustible hydrophobic zeolite, which is safer to use; The disadvantage is that the one-time investment is high.
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Small honeycomb activated carbon high quality The mutual adsorption between molecules is also called "van der Waals gravity". Although molecular motion speed is affected by temperature, material and other reasons, it always keeps moving in the micro environment. Due to the mutual attraction force between molecules, when a molecule is trapped in the inner pore volume of zeolite, it will lead to more molecules being absorbed until the adsorption of zeolite is saturated. Physical adsorption mainly occurs in the process of removing impurities from the liquid and gas phases of zeolite. The porous structure of zeolite provides a large amount of specific surface area, which makes it very easy to absorb and collect impurities. Due to the interaction of molecules, a large number of molecules on the pore wall of zeolite can generate strong gravity, just like magnetic force, So as to achieve the purpose of attracting impurities in the medium to the aperture. Small honeycomb activated carbon Shangrao Chemical adsorption In addition to physical adsorption, chemical reaction also often occurs on the surface of zeolite, which contains a small amount of chemical combination, oxygen and hydrogen in the form of functional groups. These surfaces contain oxides of earth or complexes that can react with the adsorbed substances, and then combine with the adsorbed substances to gather inside and on the surface of zeolite.
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Small honeycomb activated carbon Direct selling Microporous molecular sieves with molecular apertures below 2 nm, mesoporous molecular sieves with molecular apertures above 50 nm (macroporous molecular sieves with molecular apertures above 50 nm), mesoporous molecular sieves have high specific surface area, regular and orderly pore structure, narrow pore size distribution, continuous and adjustable pore size and other characteristics, which make it difficult to complete the adsorption and separation of macromolecules in many microporous molecular sieves, And catalytic reaction. Therefore, molecular sieve materials with different properties and pore sizes shall be configured according to the different components of organic waste gas during selection, so as to achieve targeted organic waste gas treatment, meet the design requirements and emission standards. The main material of honeycomb zeolite adsorbent is natural zeolite. The manufacturer of zeolite is composed of silica Inorganic microporous material composed of al_2o_3 and alkaline metal or alkaline earth metal, with inner pore volume accounting for 40-50% of the total volume and specific surface area of 100-500 m2/g, is characterized by high temperature resistance, non flammability, good thermal stability and hydrothermal stability. It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and can be regenerated at high temperature. Compared with honeycomb activated carbon, its performance is about 25% of its efficiency, However, it is widely used in the fields of adsorption, separation, catalysis and environment due to its high temperature resistance and difficult ignition, Small honeycomb activated carbon high quality It is more suitable for the treatment of organic waste gas with large air volume and low concentration.
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High honeycomb zeolite molecular sieve content The zeolite content of the zeolite runner is proportional to the adsorption concentration efficiency, Small honeycomb activated carbon high quality Therefore, when choosing to purchase zeolite runner, the matching zeolite content should be selected in combination with the emission concentration of enterprise exhaust gas pollutants. 2、 With good hydrophobicity, choose to purchase zeolite with large specific surface area. 2) Select inspection equipment to test the hydrophobicity of equipment Small honeycomb activated carbon Direct selling 。 When the air humidity is greater than 60%, calibrate the equipment. If the equipment is blocked and the machine works abnormally, it indicates that the equipment has poor hydrophobicity, and you should carefully consider whether to purchase the equipment.