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Honeycomb zeolite molecular sieve is a kind of aluminosilicate material containing alkali metal or alkaline earth metal oxide with open framework and regular pore cage structure. It has been widely used since it was discovered by Swedish scientists in 1956, and then it has been widely used in petrochemical industry, environmental protection, bioengineering and other fields due to its special physical characteristics. Sponge activated carbon high quality And with the gradual expansion of the demand for zeolite molecular sieves, researchers began to expand a variety of synthetic methods of zeolite molecular sieves to meet the needs of various fields. Zeolite molecular sieve has super strong adsorption performance, which is due to a "surface force" generated by molecular gravity on the solid surface. When the fluid flows, some molecules in the fluid collide with the adsorbent surface due to irregular movement, resulting in molecular concentration on the surface, reducing the number of such molecules in the fluid to separation Purposes of clearing. Sponge activated carbon manufactor Since the adsorption does not undergo chemical changes, as long as the molecules concentrated on the surface are managed to drive away, the zeolite molecular sieve will have the adsorption capacity again. This process is the reverse process of adsorption, which is called the resolution or regeneration process.
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Sponge activated carbon high quality Due to its large pore size, mesoporous materials have become a good carrier for molecular reaction with large size. However, the pore wall of mesoporous materials is amorphous, so their hydrothermal stability and thermal stability cannot meet the harsh conditions required for petrochemical applications. Because there are metal ions with low electricity price and large ion radius and water in the combined state, water molecules are continuously lost after heating, but the crystal skeleton structure remains unchanged, forming many cavities with the same size. The cavities are connected by many micropores with the same diameter. These tiny holes have uniform diameters, which can adsorb molecules smaller than the diameter of the hole into the interior of the hole, By excluding molecules larger than pores, molecules with different shapes, diameters, polarities, boiling points and saturation levels can be separated, Sponge activated carbon manufactor It has the function of "screening" molecules, so it is called molecular sieve. At present, molecular sieves are widely used in metallurgy, chemical industry, electronics, petrochemical industry, natural gas and other industries.
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The zeolite runner device is essentially a concentrator. The waste gas containing organic solvent after treatment by the runner is divided into two parts: clean air that can be discharged directly and regeneration air containing high concentration organic solvent. Sponge activated carbon Ganzhou The clean air that can be directly discharged can enter the spray paint air conditioning ventilation system for recycling; The concentration of high concentration VOCs is about 10 times that of the VOCs before entering the system. The concentrated gas is then incinerated at high temperature through the TNV recovery thermal incineration system (or other equipment). The heat generated by incineration is respectively used to heat the drying room and the zeolite wheel desorption. The heat is fully used to achieve the effect of energy conservation and emission reduction. Technical performance and characteristics: simple structure, convenient maintenance and long service life; High absorption and desorption efficiency, so that VOCss waste gas with high air volume and low concentration can be converted into low air volume and high concentration waste gas, reducing the cost of back-end final treatment equipment; The pressure drop generated by the adsorption of VOCs by the zeolite runner is extremely low, which can greatly reduce the power consumption; The overall system adopts pre assembly and modular design, which has a small space requirement and provides a continuous and unmanned control mode; Waste gas concentrated by runner, Sponge activated carbon manufactor It can meet the national emission standards; The adsorbent uses non combustible hydrophobic zeolite, which is safer to use; The disadvantage is that the one-time investment is high.
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Sponge activated carbon high quality The mutual adsorption between molecules is also called "van der Waals gravity". Although molecular motion speed is affected by temperature, material and other reasons, it always keeps moving in the micro environment. Due to the mutual attraction force between molecules, when a molecule is trapped in the inner pore volume of zeolite, it will lead to more molecules being absorbed until the adsorption of zeolite is saturated. Physical adsorption mainly occurs in the process of removing impurities from the liquid and gas phases of zeolite. The porous structure of zeolite provides a large amount of specific surface area, which makes it very easy to absorb and collect impurities. Due to the interaction of molecules, a large number of molecules on the pore wall of zeolite can generate strong gravity, just like magnetic force, So as to achieve the purpose of attracting impurities in the medium to the aperture. Sponge activated carbon Ganzhou Chemical adsorption In addition to physical adsorption, chemical reaction also often occurs on the surface of zeolite, which contains a small amount of chemical combination, oxygen and hydrogen in the form of functional groups. These surfaces contain oxides of earth or complexes that can react with the adsorbed substances, and then combine with the adsorbed substances to gather inside and on the surface of zeolite.
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Sponge activated carbon high quality The evaluation of the adsorption of zeolite depends not only on whether the specific surface area of zeolite is large enough, but also on whether the equipment is hydrophobic. When purchasing, people can choose the inspection equipment. When the air humidity for the hydrophobicity of the inspection equipment is greater than 60%, if the equipment is blocked and the machine works abnormally, people should carefully consider whether to purchase the equipment. It is important to know that the adsorption and hydrophobicity of the zeolite runner are equally important. The zeolite content of the zeolite runner is proportional to the adsorption concentration efficiency. Therefore, many people should pay more attention to whether the zeolite content of the equipment meets the requirements or is high enough when choosing to purchase the zeolite runner. On the one hand, selecting excellent equipment is also to enhance the potential value of the enterprise. Sponge activated carbon Ganzhou The adsorption and concentration technology of zeolite runner is deeply loved by enterprises because of its high efficiency and energy saving characteristics. Its changeable working environment and low cost have laid an unshakable position for zeolite runner in industry. How to select a zeolite runner with stable operation and high efficiency needs people's eyes
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Molecular sieve has clear pore cavity distribution, extremely high internal surface area (600m2/s), good thermal stability (1000 ℃), and adjustable acid site center. The acidity of molecular sieve mainly comes from three coordinated aluminum atoms and aluminum ions (AlO)+on the framework and in the pores. OH based acid sensitive site center on molecular sieve HY obtained by ion exchange, Sponge activated carbon Ganzhou The aluminum ions outside the framework will strengthen the acid site and form the L acid site center. Polyvalent cations such as Ca2+, Mg2+and La3+can show the acid site center after exchange. The reduction of transition metal ions such as Cu2+and Ag+can also form acid site centers. In general, the higher the Al/Si ratio, the higher the specific activity of OH group. The modification of zeolite acidity can introduce protons through direct exchange of dilute hydrochloric acid. This method often leads to dealumination of molecular sieve framework. So NaY will become NH4Y and then HY. Because there are uniform small internal pores in the molecular sieve structure, when the molecular linearity of reactants and products is close to the pore size of the crystal, the selectivity of the catalytic reaction often depends on the corresponding size of the molecule and pore size. Sponge activated carbon high quality This selectivity is called shape selective catalysis. There are two mechanisms leading to shape selectivity. One is caused by the difference of diffusion coefficient of molecules participating in the reaction in the pore cavity, which is called mass transfer selectivity; The other is caused by the space limitation of the transition state of the catalytic reaction, which is called transition state selectivity.