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Because there are uniform small internal pores in the molecular sieve structure, Honeycomb activated carbon Beijing When the molecular linear degree of reactants and products is close to the pore size of the crystal, the selectivity of catalytic reaction often depends on the corresponding size of the molecule and pore size. This selectivity is called shape selective catalysis. There are two mechanisms leading to shape selectivity. One is caused by the difference of diffusion coefficient of molecules participating in the reaction in the pore cavity, which is called mass transfer selectivity; The other is caused by the space limitation of the transition state of the catalytic reaction, which is called transition state selectivity. Molecular sieve has clear pore cavity distribution, extremely high internal surface area (600m2/s), good thermal stability (1000 ℃), and adjustable acid site center. The acidity of molecular sieve mainly comes from three coordinated aluminum atoms and aluminum ions (AlO)+on the framework and in the pores. The OH based acid sensitive site center on the molecular sieve HY obtained by ion exchange, and the aluminum ion outside the framework will strengthen the acid site, forming the L acid site center. Polyvalent cations such as Ca2+, Mg2+and La3+can show the acid site center after exchange. The reduction of transition metal ions such as Cu2+and Ag+can also form acid site centers. In general, the higher the Al/Si ratio, the higher the specific activity of OH group. The modification of zeolite acidity can introduce protons through direct exchange of dilute hydrochloric acid. Honeycomb activated carbon high quality This method often leads to dealumination of molecular sieve framework. So NaY will become NH4Y and then HY.
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Honeycomb activated carbon high quality Since UCC scientists invented synthetic molecular sieves in the late 1940s, UOP's molecular sieve technology has changed with each passing day. Today, UOP molecular sieve is famous for its high efficiency, low consumption and reliability. With the high adsorption capacity of UOP molecular sieve, users may reduce the loading capacity of molecular sieve and extend the adsorption cycle. More importantly, with this advantage, users can significantly reduce their investment and operating costs and reduce energy consumption. This is particularly noticeable in today's increasingly tense energy. The adsorption or repulsion function of molecular sieves is affected by the molecular electricity. Synthetic zeolite has the special function of selective adsorption according to the size and polarity of molecules, so it can dry or purify gas or liquid, Honeycomb activated carbon Beijing This is also the basis for molecular sieve separation. Synthetic zeolite can meet the extensive demand of industry for adsorption and selective products, and is also widely used in industrial separation to synthesize zeolite molecular sieves. Advantages of UOP molecular sieve
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Honeycomb activated carbon Beijing 】Zeolite adsorbent has outstanding advantages 1. Strong adsorption selectivity. The pore size of molecular sieve is uniform, and it is also an ionic adsorbent. Therefore, it can selectively adsorb according to the size and polarity of molecules. It can effectively remove ethylene, propylene and acetylene from saturated hydrocarbons, which is determined by its strong polarity. 2. Strong adsorption capacity. Even if the composition concentration of the gas is very low, it still has the adsorption capacity of. 3. It is less affected by temperature. At a higher temperature, it still has a greater adsorption capacity, while other adsorbents are greatly affected by temperature, so at the same temperature, the adsorption capacity of zeolite molecular sieve is large. 4. It can be regenerated at high temperature, with high regeneration efficiency and high safety. 5. Strong resistance to poisoning and good thermal stability. Zeolite molecular sieve is an excellent adsorbent, Honeycomb activated carbon high quality It is widely used in the production of basic organic chemical industry and petrochemical industry, as well as in the treatment of harmful gases nox、co、co2,nh3,ccl4、 Purification of water vapor and gaseous hydrocarbon waste gas; As well as air purification and deodorization in biochemical industry, paint industry, underground places, leather factories and animal breeding places; Adsorption of flue gas odor, removal of mercury vapor, etc.
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Honeycomb activated carbon high quality The operation is stable, and the exhaust gas concentration can reach the standard stably; High temperature desorption can be adopted, with high regeneration efficiency and high safety; Honeycomb zeolite is used as the adsorption carrier, with small resistance; Compact structure, small floor area of the whole equipment. Honeycomb activated carbon Beijing It has a wide range of applications and is suitable for treating various organic waste gases. Technical indicators of molecular sieve: the main material of honeycomb zeolite adsorbent is natural zeolite, and the zeolite manufacturer is mainly composed of silica Inorganic microporous material composed of al_2o_3 and alkaline metal or alkaline earth metal, with inner pore volume accounting for 40-50% of the total volume and specific surface area of 100-500 m2/g, is characterized by high temperature resistance, non flammability, good thermal stability and hydrothermal stability. It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and can be regenerated at high temperature. Compared with honeycomb activated carbon, its performance is about 25% of its efficiency, However, it is widely used in the fields of adsorption, separation, catalysis and environment due to its high temperature resistance and difficult ignition. It is more suitable for the treatment of organic waste gas with large air volume and low concentration.
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High silica zeolite type molecular sieves, this kind of zeolite has a series, and ZSM-5 is widely used, with ZSM-8 and ZSM-11 having the same structure; The other group is ZSM-21, ZSM-35 and ZSM-38. ZSM-5 is often called high silica zeolite, with the Si/Al ratio up to 50 and ZSM-8 up to 100. This group of molecular sieves also shows hydrophobic characteristics. Honeycomb activated carbon Direct selling Their structural units are similar to those of mordenite, consisting of pairs of five membered rings, with no cage like cavities and only channels. ZSM-5 has two sets of cross channels, one is straight through, the other is zigzag perpendicular to each other, both formed by ten yuan rings. The channel is oval and its window diameter is (0.55-0.60) nm. Honeycomb activated carbon high quality Zeolites belonging to the high silicon group also have silicalite-1 of all silicon type, which has the same structure as ZSM-5, and silicalite-2 is the same as ZSM-11.