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Honeycomb zeolite molecular sieve is a kind of aluminosilicate material containing alkali metal or alkaline earth metal oxide with open framework and regular pore cage structure. It has been widely used since it was discovered by Swedish scientists in 1956, and then it has been widely used in petrochemical industry, environmental protection, bioengineering and other fields due to its special physical characteristics. Coal based powdered activated carbon major And with the gradual expansion of the demand for zeolite molecular sieves, researchers began to expand a variety of synthetic methods of zeolite molecular sieves to meet the needs of various fields. Zeolite molecular sieve has super strong adsorption performance, which is due to a "surface force" generated by molecular gravity on the solid surface. When the fluid flows, some molecules in the fluid collide with the adsorbent surface due to irregular movement, resulting in molecular concentration on the surface, reducing the number of such molecules in the fluid to separation Purposes of clearing. Coal based powdered activated carbon production Since the adsorption does not undergo chemical changes, as long as the molecules concentrated on the surface are managed to drive away, the zeolite molecular sieve will have the adsorption capacity again. This process is the reverse process of adsorption, which is called the resolution or regeneration process.
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Because there are uniform small internal pores in the molecular sieve structure, Coal based powdered activated carbon Shangrao When the molecular linear degree of reactants and products is close to the pore size of the crystal, the selectivity of catalytic reaction often depends on the corresponding size of the molecule and pore size. This selectivity is called shape selective catalysis. There are two mechanisms leading to shape selectivity. One is caused by the difference of diffusion coefficient of molecules participating in the reaction in the pore cavity, which is called mass transfer selectivity; The other is caused by the space limitation of the transition state of the catalytic reaction, which is called transition state selectivity. Molecular sieve has clear pore cavity distribution, extremely high internal surface area (600m2/s), good thermal stability (1000 ℃), and adjustable acid site center. The acidity of molecular sieve mainly comes from three coordinated aluminum atoms and aluminum ions (AlO)+on the framework and in the pores. The OH based acid sensitive site center on the molecular sieve HY obtained by ion exchange, and the aluminum ion outside the framework will strengthen the acid site, forming the L acid site center. Polyvalent cations such as Ca2+, Mg2+and La3+can show the acid site center after exchange. The reduction of transition metal ions such as Cu2+and Ag+can also form acid site centers. In general, the higher the Al/Si ratio, the higher the specific activity of OH group. The modification of zeolite acidity can introduce protons through direct exchange of dilute hydrochloric acid. Coal based powdered activated carbon major This method often leads to dealumination of molecular sieve framework. So NaY will become NH4Y and then HY.
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Honeycomb zeolite molecular sieve is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution and high temperature regeneration. It is widely used in the fields of adsorption, separation, catalysis and environment, Coal based powdered activated carbon major It is more suitable for the treatment of organic waste gas with large air volume and low concentration. It is widely used in the production of basic organic chemical industry and petrochemical industry, as well as in the treatment of harmful gases, SO2 NOx、CO、CO2,NH3,CCl4、 Purification of water vapor and gaseous hydrocarbon waste gas. Strong adsorption selectivity: molecular sieve materials with different properties and pore sizes are configured for the product according to the different components of organic waste gas, so as to achieve targeted and selective treatment of organic waste gas, meet the design requirements and meet the emission standards. 2. Strong adsorption capacity: even if the gas composition concentration is very low at the mg level, it still has the adsorption capacity. The efficiency is 50% higher than that of similar activated carbon. 3. Wide adaptability of adsorption temperature: at a higher temperature, it still has a large adsorption capacity, while other adsorbents are greatly affected by temperature, so under the same temperature, the adsorption capacity of molecular sieve is large. 4. Good regeneration temperature resistance: the concentration ratio of pollutants after adsorption and concentration by molecular sieve can reach 15 to 20 times, and the concentrated waste gas can be condensed and recovered or burned at high temperature as required 5. High strength: Coal based powdered activated carbon production Products coming to the company use special framework materials to make the positive pressure strength of honeycomb zeolite reach more than 3Mpa, which can reduce damage during transportation and installation.
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Coal based powdered activated carbon major There are cavities and channels in the crystal structure of zeolite with large adsorption capacity, whose volume accounts for more than 50% of the total volume of zeolite crystals. Moreover, the micropores of zeolite are evenly distributed, and the pore size is small, which is equivalent to the molecular size of general substances. The internal surface area of zeolite crystals can reach more than 1000 square meters. Therefore, the adsorption capacity of zeolite is particularly large. The main material of honeycomb zeolite adsorbent is natural zeolite. The manufacturer of zeolite is composed of silica Inorganic microporous material composed of al_2o_3 and alkaline metal or alkaline earth metal, with inner pore volume accounting for 40-50% of the total volume and specific surface area of 100-500 m2/g, is characterized by high temperature resistance, non flammability, good thermal stability and hydrothermal stability. It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and can be regenerated at high temperature. Compared with honeycomb activated carbon, its performance is about 25% of its efficiency, However, it is widely used in the fields of adsorption, separation, catalysis and environment due to its high temperature resistance and difficult ignition. It is more suitable for the treatment of organic waste gas with large air volume and low concentration.
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Coal based powdered activated carbon major Microporous molecular sieves with molecular pore size below 2 nm and mesoporous molecular sieves with molecular pore size between 2-50 nm (50 nm The above are macroporous molecular sieves), mesoporous molecular sieves have high specific surface area, regular and orderly pore structure, narrow pore size distribution, continuous and adjustable pore size and other characteristics, which make it play an important role in the adsorption, separation and catalytic reaction of macromolecules that are difficult for many microporous molecular sieves to complete. Therefore, molecular sieve materials with different properties and pore sizes shall be configured according to the different components of organic waste gas during selection, so as to achieve targeted organic waste gas treatment, meet the design requirements and emission standards. The main material of honeycomb zeolite adsorbent is natural zeolite. The manufacturer of zeolite is composed of silica Inorganic microporous material composed of al_2o_3 and alkaline metal or alkaline earth metal, with inner pore volume accounting for 40-50% of the total volume and specific surface area of 100-500 m2/g, has the characteristics of high temperature resistance, non flammability, good thermal stability and hydrothermal stability. It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and high temperature regeneration. Compared with honeycomb activated carbon, its performance is about 25% of its efficiency Coal based powdered activated carbon Shangrao However, it is widely used in the fields of adsorption, separation, catalysis and environment due to its high temperature resistance and low ignition resistance. It is more suitable for the treatment of organic waste gas with large air volume and low concentration.
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The main components of zeolite are: silicon and aluminum, which have adsorption capacity and can be used as adsorbent; Zeolite runner is to use the specific pore size of zeolite to have the ability of adsorption and desorption for organic pollutants, so that VOCs waste gas with low concentration and large air volume can be concentrated and converted into low air volume and high concentration gas by the zeolite runner, which can reduce the operating cost of the back-end final treatment equipment. Coal based powdered activated carbon Shangrao The characteristics of the device are suitable for treating waste gas with large flow, low concentration and various organic components. The disadvantage is high initial investment. The zeolite wheel adsorption purification device is a gas purification device that can continuously perform adsorption and desorption operations. The two sides of the zeolite runner are divided into three areas by special sealing devices: adsorption area, desorption (regeneration) area and cooling area. Coal based powdered activated carbon major The working process of the system is as follows: the zeolite runner rotates continuously at a low speed and circulates through the adsorption area, desorption (regeneration) area and cooling area; When the exhaust gas with low concentration and large air volume continuously passes through the adsorption area of the runner, VOCs in the exhaust gas are adsorbed by the zeolite of the runner, and the gas purified by adsorption is directly discharged; The organic solvent adsorbed by the wheel is sent to the desorption (regeneration) area with the rotation of the runner, and then the small amount of hot air continuously passes through the desorption area. The VOCs adsorbed on the runner are thermally desorbed in the desorption area to achieve regeneration, and the VOCs waste gas is discharged together with the hot air; After the runner is transferred to the cooling area for cooling, the adsorption can be carried out again. With the continuous rotation of the runner, the adsorption, desorption and cooling cycles are carried out to ensure the continuous and stable operation of waste gas treatment.