Zeolite molecular sieves have the following potential applications. production (1) Due to the high whiteness of molecular sieves, the optical properties of paper can be improved. (2) It can improve the loose thickness and printability of the paper. (3) Molecular sieves can be used to prepare special papers such as gas filter paper, rust proof paper and photocatalysis paper due to their open structure. (4) It can be used for low weight newsprint and book paper, and can effectively avoid ink penetration. (5) Its ion exchange performance can avoid resin and filler deposition. high quality (6) It can be used for phenolic paper laminate to improve its corrosion resistance in humid environment. Phenolic paper laminates used as insulators in printed circuit boards and integrated circuits will be affected by electrolytic corrosion when exposed to high humidity. (7) It is mixed with titanium dioxide (TiO2) filler to produce high-quality white paper.
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High honeycomb zeolite molecular sieve content The zeolite content of the zeolite runner is proportional to the adsorption concentration efficiency, high quality Therefore, when choosing to purchase zeolite runner, the matching zeolite content should be selected in combination with the emission concentration of enterprise exhaust gas pollutants. 2、 With good hydrophobicity, choose to purchase zeolite with large specific surface area. 2) Select inspection equipment to test the hydrophobicity of equipment production When the air humidity is greater than 60%, calibrate the equipment. If the equipment is blocked and the machine works abnormally, it indicates that the equipment has poor hydrophobicity, and you should carefully consider whether to purchase the equipment.
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Molecular sieve has clear pore cavity distribution, extremely high internal surface area (600m2/s), good thermal stability (1000 ℃), and adjustable acid site center. The acidity of molecular sieve mainly comes from three coordinated aluminum atoms and aluminum ions (AlO)+on the framework and in the pores. OH based acid sensitive site center on molecular sieve HY obtained by ion exchange, Ganzhou The aluminum ions outside the framework will strengthen the acid site and form the L acid site center. Polyvalent cations such as Ca2+, Mg2+and La3+can show the acid site center after exchange. The reduction of transition metal ions such as Cu2+and Ag+can also form acid site centers. In general, the higher the Al/Si ratio, the higher the specific activity of OH group. The modification of zeolite acidity can introduce protons through direct exchange of dilute hydrochloric acid. This method often leads to dealumination of molecular sieve framework. So NaY will become NH4Y and then HY. Because there are uniform small internal pores in the molecular sieve structure, when the molecular linearity of reactants and products is close to the pore size of the crystal, the selectivity of the catalytic reaction often depends on the corresponding size of the molecule and pore size. high quality This selectivity is called shape selective catalysis. There are two mechanisms leading to shape selectivity. One is caused by the difference of diffusion coefficient of molecules participating in the reaction in the pore cavity, which is called mass transfer selectivity; The other is caused by the space limitation of the transition state of the catalytic reaction, which is called transition state selectivity.
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The adsorption capacity of zeolite for organic pollutants mainly depends on the polar size and molecular diameter of organic molecules. Small molecules are easier to be adsorbed than large molecules, while polar molecules are easier to be adsorbed than non-polar ones. Different substances (such as organic molecules, metal ions and water molecules) exist in water, Ganzhou Their polarity and molecular size are different, and competition will occur during adsorption. The main material of honeycomb zeolite adsorbent is natural zeolite. The manufacturer of zeolite is composed of silica Inorganic microporous material composed of al_2o_3 and alkaline metal or alkaline earth metal, with inner pore volume accounting for 40-50% of the total volume and specific surface area of 100-500 m2/g, is characterized by high temperature resistance, non flammability, good thermal stability and hydrothermal stability. It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and can be regenerated at high temperature. Compared with honeycomb activated carbon, its performance is about 25% of its efficiency, production However, it is widely used in the fields of adsorption, separation, catalysis and environment due to its high temperature resistance and difficult ignition. It is more suitable for the treatment of organic waste gas with large air volume and low concentration.
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Ganzhou Since the adsorption does not change chemically, high quality As long as we try to drive away the molecules concentrated on the surface, zeolite molecular sieves will have adsorption capacity again. This process is the reverse process of adsorption, which is called the process of desorption or regeneration. Honeycomb zeolite molecular sieve is a kind of aluminosilicate material containing alkali metal or alkaline earth metal oxide with open framework and regular pore cage structure. It has been widely used since it was discovered by Swedish scientists in 1956, and then it has been widely used in petrochemical industry, environmental protection, bioengineering and other fields due to its special physical characteristics. And with the gradual expansion of the demand for zeolite molecular sieves, researchers began to expand a variety of synthetic methods of zeolite molecular sieves to meet the needs of various fields. Zeolite molecular sieve has super strong adsorption performance, which is due to a "surface force" generated by molecular gravity on the solid surface. When the fluid flows, some molecules in the fluid collide with the adsorbent surface due to irregular movement, resulting in molecular concentration on the surface, reducing the number of such molecules in the fluid to separation Purposes of clearing