High silica zeolite type molecular sieves, this kind of zeolite has a series, and ZSM-5 is widely used, with ZSM-8 and ZSM-11 having the same structure; The other group is ZSM-21, ZSM-35 and ZSM-38. ZSM-5 is often called high silica zeolite, with the Si/Al ratio up to 50 and ZSM-8 up to 100. This group of molecular sieves also shows hydrophobic characteristics. Direct selling Their structural units are similar to those of mordenite, consisting of pairs of five membered rings, with no cage like cavities and only channels. ZSM-5 has two sets of cross channels, one is straight through, the other is zigzag perpendicular to each other, both formed by ten yuan rings. The channel is oval and its window diameter is (0.55-0.60) nm. major Zeolites belonging to the high silicon group also have silicalite-1 of all silicon type, which has the same structure as ZSM-5, and silicalite-2 is the same as ZSM-11.
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major The mutual adsorption between molecules is also called "van der Waals gravity". Although molecular motion speed is affected by temperature, material and other reasons, it always keeps moving in the micro environment. Due to the mutual attraction force between molecules, when a molecule is trapped in the inner pore volume of zeolite, it will lead to more molecules being absorbed until the adsorption of zeolite is saturated. Physical adsorption mainly occurs in the process of removing impurities from the liquid and gas phases of zeolite. The porous structure of zeolite provides a large amount of specific surface area, which makes it very easy to absorb and collect impurities. Due to the interaction of molecules, a large number of molecules on the pore wall of zeolite can generate strong gravity, just like magnetic force, So as to achieve the purpose of attracting impurities in the medium to the aperture. Hunan Chemical adsorption In addition to physical adsorption, chemical reaction also often occurs on the surface of zeolite, which contains a small amount of chemical combination, oxygen and hydrogen in the form of functional groups. These surfaces contain oxides of earth or complexes that can react with the adsorbed substances, and then combine with the adsorbed substances to gather inside and on the surface of zeolite.
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Zeolite molecular sieve is a kind of excellent adsorbent, which is widely used in the production of basic organic chemical industry and petrochemical industry, as well as in the treatment of harmful gases nox、co、co2,nh3,ccl4、 Purification of water vapor and gaseous hydrocarbon waste gas; As well as air purification and deodorization in biochemical industry, paint industry, underground places, leather factories and animal breeding places; Adsorption of flue gas odor, removal of mercury vapor, etc. The factors affecting the purification efficiency of honeycomb zeolite molecular sieves are absorption and desorption. If the waste gas adsorbed on the runner cannot be completely desorbed, the runner will become saturated after a long time, which will affect the adsorption efficiency of the zeolite runner, major The service life of zeolite will be directly affected over time.
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The main components of zeolite are: silicon and aluminum, which have adsorption capacity and can be used as adsorbent; Zeolite runner is to use the specific pore size of zeolite to have the ability of adsorption and desorption for organic pollutants, so that VOCs waste gas with low concentration and large air volume can be concentrated and converted into low air volume and high concentration gas by the zeolite runner, which can reduce the operating cost of the back-end final treatment equipment. Hunan The characteristics of the device are suitable for treating waste gas with large flow, low concentration and various organic components. The disadvantage is high initial investment. The zeolite wheel adsorption purification device is a gas purification device that can continuously perform adsorption and desorption operations. The two sides of the zeolite runner are divided into three areas by special sealing devices: adsorption area, desorption (regeneration) area and cooling area. major The working process of the system is as follows: the zeolite runner rotates continuously at a low speed and circulates through the adsorption area, desorption (regeneration) area and cooling area; When the exhaust gas with low concentration and large air volume continuously passes through the adsorption area of the runner, VOCs in the exhaust gas are adsorbed by the zeolite of the runner, and the gas purified by adsorption is directly discharged; The organic solvent adsorbed by the wheel is sent to the desorption (regeneration) area with the rotation of the runner, and then the small amount of hot air continuously passes through the desorption area. The VOCs adsorbed on the runner are thermally desorbed in the desorption area to achieve regeneration, and the VOCs waste gas is discharged together with the hot air; After the runner is transferred to the cooling area for cooling, the adsorption can be carried out again. With the continuous rotation of the runner, the adsorption, desorption and cooling cycles are carried out to ensure the continuous and stable operation of waste gas treatment.
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major In the process of removing impurities in the liquid and gas phases, the porous structure of zeolite provides a large amount of specific surface area, which makes it very easy to absorb and collect impurities. Due to the mutual adsorption of molecules, a large number of molecules on the pore wall of zeolite can generate strong gravity, just like magnetic force, So as to achieve the purpose of attracting impurities in the medium to the aperture. The main material of honeycomb zeolite adsorbent is natural zeolite. The manufacturer of zeolite is composed of silica Inorganic microporous material composed of al_2o_3 and alkaline metal or alkaline earth metal, with inner pore volume accounting for 40-50% of the total volume and specific surface area of 100-500 m2/g, is characterized by high temperature resistance, non flammability, good thermal stability and hydrothermal stability. It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and can be regenerated at high temperature. Compared with honeycomb activated carbon, its performance is about 25% of its efficiency, Direct selling However, it is widely used in the fields of adsorption, separation, catalysis and environment due to its high temperature resistance and difficult ignition. It is more suitable for the treatment of organic waste gas with large air volume and low concentration.