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Because there are uniform small internal pores in the molecular sieve structure, Honeycomb zeolite molecular sieve Pingxiang When the molecular linear degree of reactants and products is close to the pore size of the crystal, the selectivity of catalytic reaction often depends on the corresponding size of the molecule and pore size. This selectivity is called shape selective catalysis. There are two mechanisms leading to shape selectivity. One is caused by the difference of diffusion coefficient of molecules participating in the reaction in the pore cavity, which is called mass transfer selectivity; The other is caused by the space limitation of the transition state of the catalytic reaction, which is called transition state selectivity. Molecular sieve has clear pore cavity distribution, extremely high internal surface area (600m2/s), good thermal stability (1000 ℃), and adjustable acid site center. The acidity of molecular sieve mainly comes from three coordinated aluminum atoms and aluminum ions (AlO)+on the framework and in the pores. The OH based acid sensitive site center on the molecular sieve HY obtained by ion exchange, and the aluminum ion outside the framework will strengthen the acid site, forming the L acid site center. Polyvalent cations such as Ca2+, Mg2+and La3+can show the acid site center after exchange. The reduction of transition metal ions such as Cu2+and Ag+can also form acid site centers. In general, the higher the Al/Si ratio, the higher the specific activity of OH group. The modification of zeolite acidity can introduce protons through direct exchange of dilute hydrochloric acid. Honeycomb zeolite molecular sieve major This method often leads to dealumination of molecular sieve framework. So NaY will become NH4Y and then HY.
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Honeycomb zeolite molecular sieve Pingxiang Since the adsorption does not change chemically, Honeycomb zeolite molecular sieve major As long as we try to drive away the molecules concentrated on the surface, zeolite molecular sieves will have adsorption capacity again. This process is the reverse process of adsorption, which is called the process of desorption or regeneration. Honeycomb zeolite molecular sieve is a kind of aluminosilicate material containing alkali metal or alkaline earth metal oxide with open framework and regular pore cage structure. It has been widely used since it was discovered by Swedish scientists in 1956, and then it has been widely used in petrochemical industry, environmental protection, bioengineering and other fields due to its special physical characteristics. And with the gradual expansion of the demand for zeolite molecular sieves, researchers began to expand a variety of synthetic methods of zeolite molecular sieves to meet the needs of various fields. Zeolite molecular sieve has super strong adsorption performance, which is due to a "surface force" generated by molecular gravity on the solid surface. When the fluid flows, some molecules in the fluid collide with the adsorbent surface due to irregular movement, resulting in molecular concentration on the surface, reducing the number of such molecules in the fluid to separation Purposes of clearing
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The pore size of zeolite is uniform, the internal void structure is developed, the specific surface area is large, the adsorption capacity is strong, and contains a large number of invisible pore sizes. The pore size in 1g zeolite material can be expanded to the specific surface area of 500-1000m2, which is higher for special purposes. Good hydrophobicity The evaluation of the adsorption of zeolite depends not only on whether the specific surface area of zeolite is large enough, but also on whether the hydrophobicity of equipment is good. Honeycomb zeolite molecular sieve Pingxiang When purchasing, people can choose the inspection equipment. When the air humidity for the hydrophobicity of the inspection equipment is greater than 60%, if the equipment is blocked and the machine works abnormally, people should carefully consider whether to purchase the equipment. It is important to know that the adsorption and hydrophobicity of the zeolite runner are equally important. 3、 High desorption efficiency The purification efficiency of zeolite is determined by absorption on the one hand and desorption function on the other, Honeycomb zeolite molecular sieve major If the desorption efficiency of the equipment cannot meet the daily operation standard, the working efficiency of the zeolite runner will be affected if the time is long. Not only that, it will also affect the zeolite runner.
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Pingxiang Honeycomb zeolite molecular sieve Zeolite is a porous aluminosilicate crystal (a1uminsi1ict) with a water bearing frame structure, which exists naturally in nature and is also artificially synthesized. The ideal chemical formula of zeolite can be expressed as Mx/yA1XSiyO2 (x y) P? H2O, Where, M is alkali metal (such as Na, K, Li) and alkaline earth metal (such as Ca, Mg, Ba, Sr). The chemical composition of zeolite is generally considered to be composed of A12O3, SiO2, H2O and metal cations, of which A12O3 and SiO2 account for about 80% of the total zeolite minerals. In different zeolite minerals, the proportion of silicon and aluminum is different, Honeycomb zeolite molecular sieve Direct selling And the different proportion of zeolite will cause some changes in zeolite characteristics, such as ion exchange and acid resistance. Because the silicon (aluminum) oxygen tetrahedron of natural zeolite crystal has many holes and channels, which occupy cations and water molecules. When some other goods are completely dehydrated after baking, the crystal skeleton is not damaged, but forms large holes on the inner surface, which can absorb and store a large number of molecules, so it has the characteristics of large adsorption capacity and high selectivity.
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Honeycomb zeolite molecular sieve Pingxiang There are cavities and channels in the crystal structure of zeolite with large adsorption capacity, whose volume accounts for more than 50% of the total volume of zeolite crystals. Moreover, the micropores of zeolite are evenly distributed, and the pore size is small, which is equivalent to the molecular size of general substances. The internal surface area of zeolite crystals can reach more than 1000 square meters. Therefore, the adsorption capacity of zeolite is particularly large. The holes and channels inside the highly selective zeolite crystal are uniform and fixed in size, and the diameter of the holes is generally 6~15A. Honeycomb zeolite molecular sieve Direct selling Only molecules with smaller diameter can enter the cavity through the zeolite channel and be adsorbed, while large molecules cannot enter the cavity and be adsorbed. Zeolite is also called molecular sieve because of its selective adsorption performance. However, silica gel, activated carbon and other adsorbents have no selective adsorption and screening performance due to their non uniformly fixed pore sizes and large changes. Price of Shunyi zeolite filter material
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The main material of honeycomb zeolite molecular sieve is natural zeolite, which is an inorganic microporous material composed of SiO2, Al2O3 and alkaline metal or alkaline earth metal. Its inner pore volume accounts for 40-50% of the total volume, and its specific surface area is 300-1000 m2/g, which has the characteristics of high temperature resistance, non flammability, good thermal stability and hydrothermal stability, Honeycomb zeolite molecular sieve Pingxiang It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and can be regenerated at high temperature. Its efficiency is 40% higher than that of similar activated carbon. It is widely used in the fields of adsorption, separation, catalysis and environment, and is more suitable for the treatment of organic waste gas with large air volume and low concentration. Honeycomb zeolite molecular sieve major The adsorption material has a stable ozone decomposition ability, which significantly improves the decomposition efficiency of VOCs. The adsorption material first forms a special structural effect through the combination design of silver and manganese, which can decompose ozone into active oxygen atoms, and then react with VOCs molecules to form carbon dioxide and water.