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Shandong Special activated carbon for catalyst carrier Zeolite is a porous aluminosilicate crystal (a1uminsi1ict) with a water bearing frame structure, which exists naturally in nature and is also artificially synthesized. The ideal chemical formula of zeolite can be expressed as Mx/yA1XSiyO2 (x y) P? H2O, Where, M is alkali metal (such as Na, K, Li) and alkaline earth metal (such as Ca, Mg, Ba, Sr). The chemical composition of zeolite is generally considered to be composed of A12O3, SiO2, H2O and metal cations, of which A12O3 and SiO2 account for about 80% of the total zeolite minerals. In different zeolite minerals, the proportion of silicon and aluminum is different, Special activated carbon for catalyst carrier Direct selling And the different proportion of zeolite will cause some changes in zeolite characteristics, such as ion exchange and acid resistance. Because the silicon (aluminum) oxygen tetrahedron of natural zeolite crystal has many holes and channels, which occupy cations and water molecules. When some other goods are completely dehydrated after baking, the crystal skeleton is not damaged, but forms large holes on the inner surface, which can absorb and store a large number of molecules, so it has the characteristics of large adsorption capacity and high selectivity.
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Special activated carbon for catalyst carrier high quality Since UCC scientists invented synthetic molecular sieves in the late 1940s, UOP's molecular sieve technology has changed with each passing day. Today, UOP molecular sieve is famous for its high efficiency, low consumption and reliability. With the high adsorption capacity of UOP molecular sieve, users may reduce the loading capacity of molecular sieve and extend the adsorption cycle. More importantly, with this advantage, users can significantly reduce their investment and operating costs and reduce energy consumption. This is particularly noticeable in today's increasingly tense energy. The adsorption or repulsion function of molecular sieves is affected by the molecular electricity. Synthetic zeolite has the special function of selective adsorption according to the size and polarity of molecules, so it can dry or purify gas or liquid, Special activated carbon for catalyst carrier Shandong This is also the basis for molecular sieve separation. Synthetic zeolite can meet the extensive demand of industry for adsorption and selective products, and is also widely used in industrial separation to synthesize zeolite molecular sieves. Advantages of UOP molecular sieve
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Special activated carbon for catalyst carrier high quality Microporous molecular sieves with molecular pore size below 2 nm and mesoporous molecular sieves with molecular pore size between 2-50 nm (50 nm The above are macroporous molecular sieves), mesoporous molecular sieves have high specific surface area, regular and orderly pore structure, narrow pore size distribution, continuous and adjustable pore size and other characteristics, which make it play an important role in the adsorption, separation and catalytic reaction of macromolecules that are difficult for many microporous molecular sieves to complete. Therefore, molecular sieve materials with different properties and pore sizes shall be configured according to the different components of organic waste gas during selection, so as to achieve targeted organic waste gas treatment, meet the design requirements and emission standards. The main material of honeycomb zeolite adsorbent is natural zeolite. The manufacturer of zeolite is composed of silica Inorganic microporous material composed of al_2o_3 and alkaline metal or alkaline earth metal, with inner pore volume accounting for 40-50% of the total volume and specific surface area of 100-500 m2/g, has the characteristics of high temperature resistance, non flammability, good thermal stability and hydrothermal stability. It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and high temperature regeneration. Compared with honeycomb activated carbon, its performance is about 25% of its efficiency Special activated carbon for catalyst carrier Shandong However, it is widely used in the fields of adsorption, separation, catalysis and environment due to its high temperature resistance and low ignition resistance. It is more suitable for the treatment of organic waste gas with large air volume and low concentration.
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With the continuous deepening of research, honeycomb zeolite molecular sieve has gradually moved from laboratory to industrial practical application. Due to its powerful performance, it can be integrated with the reactor, Shandong Special activated carbon for catalyst carrier In membrane catalytic reaction, the reaction is coupled with separation. At present, the application fields of zeolite membrane are pervaporation, gas separation and membrane reactor. It is the needs of human practical activities and the development of application fields that constantly promote the development of zeolite molecular sieves. From natural zeolite to synthetic zeolite, from low silica zeolite to high silica zeolite; From silicoaluminium molecular sieve to aluminophosphate molecular sieve; From super micropore to mesoporous material; Special activated carbon for catalyst carrier high quality The development from inorganic porous frameworks to MOFs, as well as the recent emergence of macroporous materials, has effectively improved the yield, reduced the synthesis cost and environmental pollution.
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Special activated carbon for catalyst carrier Shandong Because the aluminum oxide tetrahedron of zeolite has a negative charge, and the skeleton hole contains cations, a strong electric field is formed around the cations. Therefore, the adsorption force of zeolite not only has a strong dispersion force, but also has a large electrostatic force. It is precisely because of this electrostatic relationship that zeolites have preferential selective adsorption on polar, unsaturated and polarizable molecules. It can strongly adsorb molecules containing polar groups such as hydroxyl ion, ammonium ion and other polarizable groups, especially water, which can form hydrogen bonds with aluminum silicon skeleton, so zeolite has strong water absorption. It can still adsorb even under low relative humidity and concentration, and its water absorption is higher than that of silica gel and activated alumina. The main material of honeycomb zeolite adsorbent is natural zeolite. The manufacturer of zeolite is composed of silica Inorganic microporous material composed of al_2o_3 and alkaline metal or alkaline earth metal, with inner pore volume accounting for 40-50% of the total volume and specific surface area of 100-500 m2/g, is characterized by high temperature resistance, non flammability, good thermal stability and hydrothermal stability. It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and can be regenerated at high temperature. Compared with honeycomb activated carbon, its performance is about 25% of its efficiency, However, it is widely used in the fields of adsorption, separation, catalysis and environment due to its high temperature resistance and difficult ignition. It is more suitable for the treatment of organic waste gas with large air volume and low concentration.
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Molecular sieve has clear pore cavity distribution, extremely high internal surface area (600m2/s), good thermal stability (1000 ℃), and adjustable acid site center. The acidity of molecular sieve mainly comes from three coordinated aluminum atoms and aluminum ions (AlO)+on the framework and in the pores. OH based acid sensitive site center on molecular sieve HY obtained by ion exchange, Special activated carbon for catalyst carrier Shandong The aluminum ions outside the framework will strengthen the acid site and form the L acid site center. Polyvalent cations such as Ca2+, Mg2+and La3+can show the acid site center after exchange. The reduction of transition metal ions such as Cu2+and Ag+can also form acid site centers. In general, the higher the Al/Si ratio, the higher the specific activity of OH group. The modification of zeolite acidity can introduce protons through direct exchange of dilute hydrochloric acid. This method often leads to dealumination of molecular sieve framework. So NaY will become NH4Y and then HY. Because there are uniform small internal pores in the molecular sieve structure, when the molecular linearity of reactants and products is close to the pore size of the crystal, the selectivity of the catalytic reaction often depends on the corresponding size of the molecule and pore size. Special activated carbon for catalyst carrier high quality This selectivity is called shape selective catalysis. There are two mechanisms leading to shape selectivity. One is caused by the difference of diffusion coefficient of molecules participating in the reaction in the pore cavity, which is called mass transfer selectivity; The other is caused by the space limitation of the transition state of the catalytic reaction, which is called transition state selectivity.