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Production of high-quality water-resistant honeycomb activated carbon in Ganzhou

2020-07-10
 Production of high-quality water-resistant honeycomb activated carbon in Ganzhou

Water resistant honeycomb activated carbon Ganzhou 】Zeolite adsorbent has outstanding advantages 1. Strong adsorption selectivity. The pore size of molecular sieve is uniform, and it is also an ionic adsorbent. Therefore, it can selectively adsorb according to the size and polarity of molecules. It can effectively remove ethylene, propylene and acetylene from saturated hydrocarbons, which is determined by its strong polarity. 2. Strong adsorption capacity. Even if the composition concentration of the gas is very low, it still has the adsorption capacity of. 3. It is less affected by temperature. At a higher temperature, it still has a greater adsorption capacity, while other adsorbents are greatly affected by temperature, so at the same temperature, the adsorption capacity of zeolite molecular sieve is large. 4. It can be regenerated at high temperature, with high regeneration efficiency and high safety. 5. Strong resistance to poisoning and good thermal stability. Zeolite molecular sieve is an excellent adsorbent, Water resistant honeycomb activated carbon high quality It is widely used in the production of basic organic chemical industry and petrochemical industry, as well as in the treatment of harmful gases nox、co、co2,nh3,ccl4、 Purification of water vapor and gaseous hydrocarbon waste gas; As well as air purification and deodorization in biochemical industry, paint industry, underground places, leather factories and animal breeding places; Adsorption of flue gas odor, removal of mercury vapor, etc.

 Production of high-quality water-resistant honeycomb activated carbon in Ganzhou

Ganzhou Water resistant honeycomb activated carbon Zeolite is a porous aluminosilicate crystal (a1uminsi1ict) with a water bearing frame structure, which exists naturally in nature and is also artificially synthesized. The ideal chemical formula of zeolite can be expressed as Mx/yA1XSiyO2 (x y) P? H2O, Where, M is alkali metal (such as Na, K, Li) and alkaline earth metal (such as Ca, Mg, Ba, Sr). The chemical composition of zeolite is generally considered to be composed of A12O3, SiO2, H2O and metal cations, of which A12O3 and SiO2 account for about 80% of the total zeolite minerals. In different zeolite minerals, the proportion of silicon and aluminum is different, Water resistant honeycomb activated carbon production And the different proportion of zeolite will cause some changes in zeolite characteristics, such as ion exchange and acid resistance. Because the silicon (aluminum) oxygen tetrahedron of natural zeolite crystal has many holes and channels, which occupy cations and water molecules. When some other goods are completely dehydrated after baking, the crystal skeleton is not damaged, but forms large holes on the inner surface, which can absorb and store a large number of molecules, so it has the characteristics of large adsorption capacity and high selectivity.

 Production of high-quality water-resistant honeycomb activated carbon in Ganzhou

Zeolite molecular sieve is a kind of excellent adsorbent, which is widely used in the production of basic organic chemical industry and petrochemical industry, as well as in the treatment of harmful gases nox、co、co2,nh3,ccl4、 Purification of water vapor and gaseous hydrocarbon waste gas; As well as air purification and deodorization in biochemical industry, paint industry, underground places, leather factories and animal breeding places; Adsorption of flue gas odor, removal of mercury vapor, etc. The factors affecting the purification efficiency of honeycomb zeolite molecular sieves are absorption and desorption. If the waste gas adsorbed on the runner cannot be completely desorbed, the runner will become saturated after a long time, which will affect the adsorption efficiency of the zeolite runner, Water resistant honeycomb activated carbon high quality The service life of zeolite will be directly affected over time.

 Production of high-quality water-resistant honeycomb activated carbon in Ganzhou

Molecular sieve has clear pore cavity distribution, extremely high internal surface area (600m2/s), good thermal stability (1000 ℃), and adjustable acid site center. The acidity of molecular sieve mainly comes from three coordinated aluminum atoms and aluminum ions (AlO)+on the framework and in the pores. OH based acid sensitive site center on molecular sieve HY obtained by ion exchange, Water resistant honeycomb activated carbon Ganzhou The aluminum ions outside the framework will strengthen the acid site and form the L acid site center. Polyvalent cations such as Ca2+, Mg2+and La3+can show the acid site center after exchange. The reduction of transition metal ions such as Cu2+and Ag+can also form acid site centers. In general, the higher the Al/Si ratio, the higher the specific activity of OH group. The modification of zeolite acidity can introduce protons through direct exchange of dilute hydrochloric acid. This method often leads to dealumination of molecular sieve framework. So NaY will become NH4Y and then HY. Because there are uniform small internal pores in the molecular sieve structure, when the molecular linearity of reactants and products is close to the pore size of the crystal, the selectivity of the catalytic reaction often depends on the corresponding size of the molecule and pore size. Water resistant honeycomb activated carbon high quality This selectivity is called shape selective catalysis. There are two mechanisms leading to shape selectivity. One is caused by the difference of diffusion coefficient of molecules participating in the reaction in the pore cavity, which is called mass transfer selectivity; The other is caused by the space limitation of the transition state of the catalytic reaction, which is called transition state selectivity.

 Production of high-quality water-resistant honeycomb activated carbon in Ganzhou

Water resistant honeycomb activated carbon high quality The highly effective selective adsorption is due to the fact that the alumina tetrahedron of zeolite has a negative charge, while the skeleton hole contains cations, which forms a strong electric field around the cations. Therefore, the adsorption force of zeolite not only has a strong dispersion force, but also has a large electrostatic force. It is precisely because of this electrostatic relationship that zeolites have preferential selective adsorption on polar, unsaturated and polarizable molecules. It can strongly adsorb molecules containing polar groups such as hydroxyl ion, ammonium ion and other polarizable groups, especially water, which can form hydrogen bonds with aluminum silicon skeleton, so zeolite has strong water absorption. It can still adsorb even under low relative humidity and concentration, and its water absorption is higher than that of silica gel and activated alumina. The adsorption capacity of zeolite for organic pollutants mainly depends on the polar size and molecular diameter of organic molecules. Small molecules are easier to be adsorbed than large molecules, while polar molecules are easier to be adsorbed than non-polar ones. Different substances (such as organic molecules, metal ions and water molecules) exist in water, Water resistant honeycomb activated carbon production Their polarity and molecular size are different, and competition will occur during adsorption.

 Production of high-quality water-resistant honeycomb activated carbon in Ganzhou

Water resistant honeycomb activated carbon high quality In addition to physical adsorption, chemical reaction also often occurs on the surface of zeolite, which contains a small amount of chemical combination, oxygen and hydrogen in the form of functional groups. These surfaces contain oxides or complexes that can react with the adsorbed substances, so that they can combine with the adsorbed substances and aggregate to the interior and surface of zeolite. Water resistant honeycomb activated carbon Ganzhou The main material of honeycomb zeolite adsorbent is natural zeolite. The manufacturer of zeolite is composed of silica Inorganic microporous material composed of al_2o_3 and alkaline metal or alkaline earth metal, with inner pore volume accounting for 40-50% of the total volume and specific surface area of 100-500 m2/g, is characterized by high temperature resistance, non flammability, good thermal stability and hydrothermal stability. It is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution, and can be regenerated at high temperature. Compared with honeycomb activated carbon, its performance is about 25% of its efficiency, However, it is widely used in the fields of adsorption, separation, catalysis and environment due to its high temperature resistance and difficult ignition. It is more suitable for the treatment of organic waste gas with large air volume and low concentration.