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The holes and channels inside the zeolite crystal are uniform and fixed in size, and the diameter of the holes is generally 6~15A. Coal based powdered activated carbon Jingdezhen Only molecules with smaller diameter can enter the cavity through the zeolite channel and be adsorbed, while large molecules cannot enter the cavity and be adsorbed. Zeolite is also called molecular sieve because of its selective adsorption performance. However, silica gel, activated carbon and other adsorbents have no selective adsorption and screening performance due to their non uniformly fixed pore sizes and large changes. Shunyi zeolite filter material price. Because the silicon (aluminum) oxygen tetrahedron of natural zeolite crystal has many holes and channels, which occupy cations and water molecules. When some other goods are completely dehydrated after baking, the crystal skeleton is not damaged, but forms large holes on the inner surface, which can absorb and store a large number of molecules, so it has the characteristics of large adsorption capacity and high selectivity. Coal based powdered activated carbon purchase In different zeolite minerals, the proportion of silicon and aluminum is different, and the different proportion will cause some characteristics of zeolite changes, such as ion exchange and acid resistance.
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Because there are uniform small internal pores in the molecular sieve structure, Coal based powdered activated carbon Jingdezhen When the molecular linear degree of reactants and products is close to the pore size of the crystal, the selectivity of catalytic reaction often depends on the corresponding size of the molecule and pore size. This selectivity is called shape selective catalysis. There are two mechanisms leading to shape selectivity. One is caused by the difference of diffusion coefficient of molecules participating in the reaction in the pore cavity, which is called mass transfer selectivity; The other is caused by the space limitation of the transition state of the catalytic reaction, which is called transition state selectivity. Molecular sieve has clear pore cavity distribution, extremely high internal surface area (600m2/s), good thermal stability (1000 ℃), and adjustable acid site center. The acidity of molecular sieve mainly comes from three coordinated aluminum atoms and aluminum ions (AlO)+on the framework and in the pores. The OH based acid sensitive site center on the molecular sieve HY obtained by ion exchange, and the aluminum ion outside the framework will strengthen the acid site, forming the L acid site center. Polyvalent cations such as Ca2+, Mg2+and La3+can show the acid site center after exchange. The reduction of transition metal ions such as Cu2+and Ag+can also form acid site centers. In general, the higher the Al/Si ratio, the higher the specific activity of OH group. The modification of zeolite acidity can introduce protons through direct exchange of dilute hydrochloric acid. Coal based powdered activated carbon purchase This method often leads to dealumination of molecular sieve framework. So NaY will become NH4Y and then HY.
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Zeolite molecular sieve is a kind of excellent adsorbent, which is widely used in the production of basic organic chemical industry and petrochemical industry, as well as in the treatment of harmful gases nox、co、co2,nh3,ccl4、 Purification of water vapor and gaseous hydrocarbon waste gas; As well as air purification and deodorization in biochemical industry, paint industry, underground places, leather factories and animal breeding places; Adsorption of flue gas odor, removal of mercury vapor, etc. The factors affecting the purification efficiency of honeycomb zeolite molecular sieves are absorption and desorption. If the waste gas adsorbed on the runner cannot be completely desorbed, the runner will become saturated after a long time, which will affect the adsorption efficiency of the zeolite runner, Coal based powdered activated carbon purchase The service life of zeolite will be directly affected over time.
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The zeolite wheel adsorption purification device is a gas purification device that can continuously perform adsorption and desorption operations. Coal based powdered activated carbon purchase The two sides of the zeolite runner are divided into three areas by special sealing devices: adsorption area, desorption (regeneration) area and cooling area. The working process of the system is as follows: the zeolite runner rotates continuously at a low speed and circulates through the adsorption area, desorption (regeneration) area and cooling area; When the exhaust gas with low concentration and large air volume continuously passes through the adsorption area of the runner, VOCs in the exhaust gas are adsorbed by the zeolite of the runner, and the gas purified by adsorption is directly discharged; The organic solvent adsorbed by the wheel is sent to the desorption (regeneration) area along with the rotation of the wheel, and then continuously passes through the desorption area with small amount of hot air, purchase Jingdezhen VOCs adsorbed on the runner are thermally desorbed in the desorption area to achieve regeneration, and VOCs waste gas is discharged with hot air; After the runner is transferred to the cooling area for cooling, it can be re adsorbed. With the continuous rotation of the runner, adsorption, desorption and cooling cycles are carried out to ensure the continuous and stable operation of waste gas treatment
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The zeolite runner device is essentially a concentrator. The waste gas containing organic solvent after treatment by the runner is divided into two parts: clean air that can be discharged directly and regeneration air containing high concentration organic solvent. Coal based powdered activated carbon Jingdezhen The clean air that can be directly discharged can enter the spray paint air conditioning ventilation system for recycling; The concentration of high concentration VOCs is about 10 times that of the VOCs before entering the system. The concentrated gas is then incinerated at high temperature through the TNV recovery thermal incineration system (or other equipment). The heat generated by incineration is respectively used to heat the drying room and the zeolite wheel desorption. The heat is fully used to achieve the effect of energy conservation and emission reduction. Technical performance and characteristics: simple structure, convenient maintenance and long service life; High absorption and desorption efficiency, so that VOCss waste gas with high air volume and low concentration can be converted into low air volume and high concentration waste gas, reducing the cost of back-end final treatment equipment; The pressure drop generated by the adsorption of VOCs by the zeolite runner is extremely low, which can greatly reduce the power consumption; The overall system adopts pre assembly and modular design, which has a small space requirement and provides a continuous and unmanned control mode; Waste gas concentrated by runner, Coal based powdered activated carbon Direct selling It can meet the national emission standards; The adsorbent uses non combustible hydrophobic zeolite, which is safer to use; The disadvantage is that the one-time investment is high.