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The holes and channels inside the zeolite crystal are uniform and fixed in size, and the diameter of the holes is generally 6~15A. Air purification activated carbon Chongqing Only molecules with smaller diameter can enter the cavity through the zeolite channel and be adsorbed, while large molecules cannot enter the cavity and be adsorbed. Zeolite is also called molecular sieve because of its selective adsorption performance. However, silica gel, activated carbon and other adsorbents have no selective adsorption and screening performance due to their non uniformly fixed pore sizes and large changes. Shunyi zeolite filter material price. Because the silicon (aluminum) oxygen tetrahedron of natural zeolite crystal has many holes and channels, which occupy cations and water molecules. When some other goods are completely dehydrated after baking, the crystal skeleton is not damaged, but forms large holes on the inner surface, which can absorb and store a large number of molecules, so it has the characteristics of large adsorption capacity and high selectivity. Air purification activated carbon high quality In different zeolite minerals, the proportion of silicon and aluminum is different, and the different proportion will cause some characteristics of zeolite changes, such as ion exchange and acid resistance.
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Molecular sieve is a crystalline silicate or aluminosilicate, which is a pore and cavity system with molecular size (usually 0.3nm to 2.0nm) formed by connecting silicon oxygen tetrahedron or aluminum oxide tetrahedron through oxygen bridge bond, Air purification activated carbon Chongqing Therefore, it has the characteristics of screening molecules. However, with the deepening of molecular sieve synthesis and application research, researchers have found phosphoaluminate molecular sieves, and the skeleton elements (silicon or aluminum or phosphorus) of molecular sieves can also be replaced by B, Ga, Fe, Cr, Ge, Ti, V, Mn, Co, Zn, Be and Cu, and the size of its pores and cavities can also reach more than 2 nm, Air purification activated carbon high quality Therefore, molecular sieves can be divided into silicon aluminum molecular sieves, phosphorus aluminum molecular sieves and skeleton heteroatom molecular sieves according to the composition of skeleton elements;
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Because there are uniform small internal pores in the molecular sieve structure, Air purification activated carbon Chongqing When the molecular linear degree of reactants and products is close to the pore size of the crystal, the selectivity of catalytic reaction often depends on the corresponding size of the molecule and pore size. This selectivity is called shape selective catalysis. There are two mechanisms leading to shape selectivity. One is caused by the difference of diffusion coefficient of molecules participating in the reaction in the pore cavity, which is called mass transfer selectivity; The other is caused by the space limitation of the transition state of the catalytic reaction, which is called transition state selectivity. Molecular sieve has clear pore cavity distribution, extremely high internal surface area (600m2/s), good thermal stability (1000 ℃), and adjustable acid site center. The acidity of molecular sieve mainly comes from three coordinated aluminum atoms and aluminum ions (AlO)+on the framework and in the pores. The OH based acid sensitive site center on the molecular sieve HY obtained by ion exchange, and the aluminum ion outside the framework will strengthen the acid site, forming the L acid site center. Polyvalent cations such as Ca2+, Mg2+and La3+can show the acid site center after exchange. The reduction of transition metal ions such as Cu2+and Ag+can also form acid site centers. In general, the higher the Al/Si ratio, the higher the specific activity of OH group. The modification of zeolite acidity can introduce protons through direct exchange of dilute hydrochloric acid. Air purification activated carbon high quality This method often leads to dealumination of molecular sieve framework. So NaY will become NH4Y and then HY.
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Air purification activated carbon high quality Since UCC scientists invented synthetic molecular sieves in the late 1940s, UOP's molecular sieve technology has changed with each passing day. Today, UOP molecular sieve is famous for its high efficiency, low consumption and reliability. With the high adsorption capacity of UOP molecular sieve, users may reduce the loading capacity of molecular sieve and extend the adsorption cycle. More importantly, with this advantage, users can significantly reduce their investment and operating costs and reduce energy consumption. This is particularly noticeable in today's increasingly tense energy. The adsorption or repulsion function of molecular sieves is affected by the molecular electricity. Synthetic zeolite has the special function of selective adsorption according to the size and polarity of molecules, so it can dry or purify gas or liquid, Air purification activated carbon Chongqing This is also the basis for molecular sieve separation. Synthetic zeolite can meet the extensive demand of industry for adsorption and selective products, and is also widely used in industrial separation to synthesize zeolite molecular sieves. Advantages of UOP molecular sieve
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Honeycomb zeolite molecular sieve is an efficient molecular sieve carrier with good adsorption performance, no secondary pollution and high temperature regeneration. It is widely used in the fields of adsorption, separation, catalysis and environment, Air purification activated carbon high quality It is more suitable for the treatment of organic waste gas with large air volume and low concentration. It is widely used in the production of basic organic chemical industry and petrochemical industry, as well as in the treatment of harmful gases, SO2 NOx、CO、CO2,NH3,CCl4、 Purification of water vapor and gaseous hydrocarbon waste gas. Strong adsorption selectivity: molecular sieve materials with different properties and pore sizes are configured for the product according to the different components of organic waste gas, so as to achieve targeted and selective treatment of organic waste gas, meet the design requirements and meet the emission standards. 2. Strong adsorption capacity: even if the gas composition concentration is very low at the mg level, it still has the adsorption capacity. The efficiency is 50% higher than that of similar activated carbon. 3. Wide adaptability of adsorption temperature: at a higher temperature, it still has a large adsorption capacity, while other adsorbents are greatly affected by temperature, so under the same temperature, the adsorption capacity of molecular sieve is large. 4. Good regeneration temperature resistance: the concentration ratio of pollutants after adsorption and concentration by molecular sieve can reach 15 to 20 times, and the concentrated waste gas can be condensed and recovered or burned at high temperature as required 5. High strength: Air purification activated carbon production Products coming to the company use special framework materials to make the positive pressure strength of honeycomb zeolite reach more than 3Mpa, which can reduce damage during transportation and installation.
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Chongqing Air purification activated carbon Zeolite is a porous aluminosilicate crystal (a1uminsi1ict) with a water bearing frame structure, which exists naturally in nature and is also artificially synthesized. The ideal chemical formula of zeolite can be expressed as Mx/yA1XSiyO2 (x y) P? H2O, Where, M is alkali metal (such as Na, K, Li) and alkaline earth metal (such as Ca, Mg, Ba, Sr). The chemical composition of zeolite is generally considered to be composed of A12O3, SiO2, H2O and metal cations, of which A12O3 and SiO2 account for about 80% of the total zeolite minerals. In different zeolite minerals, the proportion of silicon and aluminum is different, Air purification activated carbon production And the different proportion of zeolite will cause some changes in zeolite characteristics, such as ion exchange and acid resistance. Because the silicon (aluminum) oxygen tetrahedron of natural zeolite crystal has many holes and channels, which occupy cations and water molecules. When some other goods are completely dehydrated after baking, the crystal skeleton is not damaged, but forms large holes on the inner surface, which can absorb and store a large number of molecules, so it has the characteristics of large adsorption capacity and high selectivity.