
Honeycomb zeolite molecular sieve high quality The highly effective selective adsorption is due to the fact that the alumina tetrahedron of zeolite has a negative charge, while the skeleton hole contains cations, which forms a strong electric field around the cations. Therefore, the adsorption force of zeolite not only has a strong dispersion force, but also has a large electrostatic force. It is precisely because of this electrostatic relationship that zeolites have preferential selective adsorption on polar, unsaturated and polarizable molecules. It can strongly adsorb molecules containing polar groups such as hydroxyl ion, ammonium ion and other polarizable groups, especially water, which can form hydrogen bonds with aluminum silicon skeleton, so zeolite has strong water absorption. It can still adsorb even under low relative humidity and concentration, and its water absorption is higher than that of silica gel and activated alumina. The adsorption capacity of zeolite for organic pollutants mainly depends on the polar size and molecular diameter of organic molecules. Small molecules are easier to be adsorbed than large molecules, while polar molecules are easier to be adsorbed than non-polar ones. Different substances (such as organic molecules, metal ions and water molecules) exist in water, Honeycomb zeolite molecular sieve production Their polarity and molecular size are different, and competition will occur during adsorption.

Honeycomb zeolite molecular sieve high quality Rely on its own unique void structure. The pore size of zeolite is uniform, the internal void structure is developed, the specific surface area is large, the adsorption capacity is strong, and contains a large number of invisible pore sizes. The pore size in 1g zeolite material can be expanded to the specific surface area of 500-1000m2, which is higher for special purposes. The mutual adsorption between molecules is also called "van der Waals gravity". Although molecular motion speed is affected by temperature, material and other factors, Honeycomb zeolite molecular sieve production But it always keeps moving in the micro environment. Due to the mutual attraction force between molecules, when a molecule is trapped in the inner pore volume of zeolite, it will lead to more molecules being absorbed until the adsorption of zeolite is saturated.

Molecular sieve has clear pore cavity distribution, extremely high internal surface area (600m2/s), good thermal stability (1000 ℃), and adjustable acid site center. The acidity of molecular sieve mainly comes from three coordinated aluminum atoms and aluminum ions (AlO)+on the framework and in the pores. OH based acid sensitive site center on molecular sieve HY obtained by ion exchange, Honeycomb zeolite molecular sieve Ji'an The aluminum ions outside the framework will strengthen the acid site and form the L acid site center. Polyvalent cations such as Ca2+, Mg2+and La3+can show the acid site center after exchange. The reduction of transition metal ions such as Cu2+and Ag+can also form acid site centers. In general, the higher the Al/Si ratio, the higher the specific activity of OH group. The modification of zeolite acidity can introduce protons through direct exchange of dilute hydrochloric acid. This method often leads to dealumination of molecular sieve framework. So NaY will become NH4Y and then HY. Because there are uniform small internal pores in the molecular sieve structure, when the molecular linearity of reactants and products is close to the pore size of the crystal, the selectivity of the catalytic reaction often depends on the corresponding size of the molecule and pore size. Honeycomb zeolite molecular sieve high quality This selectivity is called shape selective catalysis. There are two mechanisms leading to shape selectivity. One is caused by the difference of diffusion coefficient of molecules participating in the reaction in the pore cavity, which is called mass transfer selectivity; The other is caused by the space limitation of the transition state of the catalytic reaction, which is called transition state selectivity.

With the continuous deepening of research, honeycomb zeolite molecular sieve has gradually moved from laboratory to industrial practical application. Due to its powerful performance, it can be integrated with the reactor, Ji'an Honeycomb zeolite molecular sieve In membrane catalytic reaction, the reaction is coupled with separation. At present, the application fields of zeolite membrane are pervaporation, gas separation and membrane reactor. It is the needs of human practical activities and the development of application fields that constantly promote the development of zeolite molecular sieves. From natural zeolite to synthetic zeolite, from low silica zeolite to high silica zeolite; From silicoaluminium molecular sieve to aluminophosphate molecular sieve; From super micropore to mesoporous material; Honeycomb zeolite molecular sieve high quality The development from inorganic porous frameworks to MOFs, as well as the recent emergence of macroporous materials, has effectively improved the yield, reduced the synthesis cost and environmental pollution.

Honeycomb zeolite molecular sieve high quality (1) Due to the high whiteness of molecular sieves, the optical properties of paper can be improved. (2) It can improve the loose thickness and printability of the paper. (3) Molecular sieves can be used to prepare special papers such as gas filter paper, rust proof paper and photocatalysis paper due to their open structure. (4) It can be used for low weight newsprint and book paper, and can effectively avoid ink penetration. (5) Its ion exchange performance can avoid resin and filler deposition. (6) Honeycomb zeolite molecular sieve Ji'an It can be used for phenolic paper laminate to improve its corrosion resistance in humid environment. Phenolic paper laminates used as insulators in printed circuit boards and integrated circuits will be affected by electrolytic corrosion when exposed to high humidity. (7) It is mixed with titanium dioxide (TiO2) filler to produce high-quality white paper. Zeolite molecular sieve is a kind of excellent adsorbent, which is widely used in the production of basic organic chemical industry and petrochemical industry, as well as in the treatment of harmful gases nox、co、co2,nh3,ccl4、 Purification of water vapor and gaseous hydrocarbon waste gas; As well as air purification and deodorization in biochemical industry, paint industry, underground places, leather factories and animal breeding places; Adsorption of flue gas odor, removal of mercury vapor, etc.